112849-15-7 Usage
Description
(2-Cyclopropyl-2-oxoethyl)triphenyl-phosphoniuM BroMide is a white solid that serves as a reactant in the preparation of Vitamin D2 (V676040) derivatives. (2-Cyclopropyl-2-oxoethyl)triphenyl-phosphoniuM BroMide is characterized by its unique structure, which includes a cyclopropyl group attached to a 2-oxoethyl moiety, as well as a triphenyl-phosphonium bromide group. Its chemical properties make it a valuable component in the synthesis of Vitamin D2 analogs, which have potential applications in various fields.
Uses
Used in Pharmaceutical Industry:
(2-Cyclopropyl-2-oxoethyl)triphenyl-phosphoniuM BroMide is used as a reactant for the preparation of Vitamin D2 (V676040) derivatives, which are important compounds in the pharmaceutical industry. These derivatives have potential applications in the development of drugs for the treatment of various diseases, including cancer, autoimmune disorders, and bone-related conditions.
Used in Chemical Synthesis:
(2-Cyclopropyl-2-oxoethyl)triphenyl-phosphoniuM BroMide is also used as a reactant in chemical synthesis processes. Its unique structure allows it to participate in various chemical reactions, enabling the production of a wide range of compounds with diverse applications in different industries.
Check Digit Verification of cas no
The CAS Registry Mumber 112849-15-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,2,8,4 and 9 respectively; the second part has 2 digits, 1 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 112849-15:
(8*1)+(7*1)+(6*2)+(5*8)+(4*4)+(3*9)+(2*1)+(1*5)=117
117 % 10 = 7
So 112849-15-7 is a valid CAS Registry Number.
112849-15-7Relevant articles and documents
A Ba/Pd Catalytic System Enables Dehydrative Cross-Coupling and Excellent E-Selective Wittig Reactions
Xie, Peizhong,Fu, Weishan,Cai, Xinying,Sun, Zuolian,Wu, Ying,Li, Shuangshuang,Gao, Cuiqing,Yang, Xiaobo,Loh, Teck-Peng
supporting information, p. 7055 - 7059 (2019/09/12)
A Ba/Pd cooperative catalysis system was developed to enable the dehydrative cross-coupling of allylic alcohols with P-ylides to occur directly and promote a subsequent Wittig reaction in one pot. A variety of multisubstituted 1,4-dienes were isolated in good to excellent yields with broad P-ylides (stabilized by both ester and ketone carbonyl groups) and aldehyde (aliphatic and aromatic) substrates with excellent E selectivity.
Synthesis of Polysubstituted Pyridines via a One-Pot Metal-Free Strategy
Wei, Hongbo,Li, Yun,Xiao, Ke,Cheng, Bin,Wang, Huifei,Hu, Lin,Zhai, Hongbin
supporting information, p. 5974 - 5977 (2016/01/09)
An efficient strategy for the one-pot synthesis of polysubstituted pyridines via a cascade reaction from aldehydes, phosphorus ylides, and propargyl azide is reported. The reaction sequence involves a Wittig reaction, a Staudinger reaction, an aza-Wittig reaction, a 6π-3-azatriene electrocyclization, and a 1,3-H shift. This protocol provides quick access to the polysubstituted pyridines from readily available substrates in good to excellent yields.
Synthesis of MC 903, a biologically active vitamin D metabolite analogue
Calverley
, p. 4609 - 4619,4609-4619 (2007/10/02)
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