6068-69-5

Basic information

• Product Name: N-sec-butylaniline
• Synonyms: N-sec-butylaniline;Aniline, N-sec-butyl-;Benzenamine, N-(1-methylpropyl)-;Nsc76563
• CAS NO: 6068-69-5
• Molecular Formula: C2H5(CH3)CHNHC6H5
• Molecular Weight: 149.2328
• Mol File: 6068-69-5.mol
• Article Data: 43

Chemical Properties

• Melting Point: 1.08°C (estimate)
• Boiling Point: 240.76°C (estimate)
• Flash Point: 93.3°C
• Appearance: /
• Density: 0.9529 (estimate)
• Vapor Pressure: 0.0885mmHg at 25°C
• Refractive Index: 1.5333
• CAS DataBase Reference: N-sec-butylaniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-sec-butylaniline(6068-69-5)
• EPA Substance Registry System: N-sec-butylaniline(6068-69-5)

Safety Data

• Hazardous Substances Data: 6068-69-5(Hazardous Substances Data)

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 36, p. 1841, 1971 DOI: 10.1021/jo00812a030

InChI:InChI=1/C10H15N/c1-3-9(2)11-10-7-5-4-6-8-10/h4-9,11H,3H2,1-2H3

Upstream product

• 78-86-4 s-butyl chloride 
• 62-53-3 aniline 
• 78-76-2 s-butyl bromide 
• 40296-03-5 N²-phenyl-2-butanimine 
• 78-93-3 butanone 
• 78-92-2 iso-butanol 
• 513-48-4 2-butyl iodide 
• 98-95-3 nitrobenzene 
• 108-86-1 bromobenzene 
• 33966-50-6 SEC-BUTYLAMINE 
• 52615-84-6 N-chloro-sec-butylamine 
• 100-58-3 phenylmagnesium bromide 
• 98-80-6 phenylboronic acid 
• 106-98-9 1-butylene 

Downstream Products

• 84695-43-2 1-(1-methylpropyl)-1-phenylhydrazine 
• 67651-62-1 N-sec-Butyl-N-alkyl-3,4-dichlorbenzamid 
• 72411-06-4 1-sec-Butyl-1-phenyl-3-phenylacetyl-thiourea 
• 55239-86-6 C₁₁H₁₄ClNO 
• 101582-56-3 N-sec-butyl-toluene-4-sulfonanilide 
• 32797-02-7 N-sec-butyl-N-nitroso-aniline 
• 101289-90-1 N-sec-butyl-N-nitroso-4-phenylazo-aniline 
• 25012-18-4 2-(N-sec-butyl-anilino)-ethanol 

Relevant articles and documents

Titanium-Catalyzed Hydroaminoalkylation of Ethylene

The first examples of titanium-catalyzed hydroaminoalkylation reactions of ethylene with secondary amines are presented. The reactions can be achieved with various titanium catalysts and they do not require the use of high pressure equipment. In addition, the first solid-state structure of a titanapyrrolidine that is formed by insertion of an alkene into the Ti?C bond of a titanaaziridine is reported.

A Highly Active PN3 Manganese Pincer Complex Performing N-Alkylation of Amines under Mild Conditions

A highly active Mn(I) catalyst based on a nonsymmetric PN3-ligand scaffold for the N-alkylation of amines with alcohols utilizing the borrowing hydrogen methodology is reported. A broad range of anilines and the more challenging aliphatic amines were alkylated with primary and secondary alcohols. Moreover, the combination of low catalyst loadings and mild reaction conditions provides high efficiency for this atom-economic transformation.

N-Alkylation of Aniline and Its Derivatives by Alcohols in the Presence of Copper Compounds

N-Alkyl- and N,N-dialkyl-substituted anilines were obtained in the reaction of aniline and its derivatives with primary and secondary alcohols in the presence of catalysts CuCl2·2H2O, CuBr2 and halomethanes as promoters.