61077-65-4

Basic information

• Product Name: 2-Phenyl-4-penten-2-ol
• CAS NO: 61077-65-4
• Molecular Formula: C₁₁H₁₄O
• Molecular Weight: 162.232
• Mol File: 61077-65-4.mol
• Article Data: 79

Chemical Properties

• Boiling Point: 257.6°Cat760mmHg
• Flash Point: 108.9°C
• Density: 0.981g/cm³
• CAS DataBase Reference: 2-Phenyl-4-penten-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Phenyl-4-penten-2-ol(61077-65-4)
• EPA Substance Registry System: 2-Phenyl-4-penten-2-ol(61077-65-4)

Safety Data

• Hazardous Substances Data: 61077-65-4(Hazardous Substances Data)

Upstream product

• 96-09-3 styrene oxide 
• 1802-55-7 diallylzinc 
• 122-78-1 phenylacetaldehyde 
• 762-72-1 allyl-trimethyl-silane 
• 4436-24-2 1,2-epoxy-3-phenylpropane 
• 104747-24-2 (vinyl)Cu*BF₃ 
• 2622-05-1 allylmagnesium bromide 
• 67242-59-5 N-methyl-N-(2-pyridyl)-formamide 
• 6921-34-2 benzylmagnesium chloride 
• 7393-43-3 tetraallyl tin 
• 101-48-4 phenylacetaldehyde dimethyl acetal 
• 591-87-7 Allyl acetate 
• 107-05-1 3-chloroprop-1-ene 
• 4861-85-2 isopropyl phenylacetate 

Downstream Products

• 122293-86-1 (R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (R)-1-benzyl-but-3-enyl ester 
• 1150313-06-6 (R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (S)-1-benzyl-but-3-enyl ester 
• 176787-12-5 3-Hydroxy-4-phenyl-butyraldehyde 
• 202933-83-3 Allyl-(1-benzyl-but-3-enyloxy)-dimethyl-silane 
• 81096-91-5 (±)-4-phenylbutane-1,3-diol 
• 873872-93-6 1-phenylpent-4-en-2-yl (E,E)-di(propen-1-yl)phosphinate 
• 345895-24-1 1-phenyl-2-(octyloxy)-4-pentene 
• 949171-58-8 1-benzylbut-3-enyl methacrylate 
• 1218948-44-7 C₁₁H₁₃Cl₂O₂P 
• 1150312-94-9 (R)-1-phenylpent-4-en-2-yl acetate 
• 122332-14-3 (S)-1-phenylpent-4-en-2-ol 
• 1265632-29-8 6-phenylhexane-1,5-diol 

Relevant articles and documents

Stereospecific Intramolecular Reductive Cross-Electrophile Coupling Reactions for Cyclopropane Synthesis

The stereospecific reductive cross-electrophile coupling reaction of 2-aryl-4-chlorotetrahydropyrans to afford disubstituted cyclopropanes is reported. This ring contraction presents surprises with respect to the stereochemical outcome of reaction of the

Triphosgene-pyridine mediated stereoselective chlorination of acyclic aliphatic 1,3-diols

We describe a strategy to chlorinate stereocomplementary acyclic aliphatic 1,3-diols using a mixture of triphosgene and pyridine. While 1,3-anti diols readily led to 1,3-anti dichlorides, 1,3-syn diols must be converted to 1,3-syn diol monosilylethers to access the corresponding 1,3-syn dichlorides. These dichlorination protocols were operationally simple, very mild, and readily tolerated by advanced synthetic intermediates.

Nickel-Catalyzed Reductive Allylation of Aldehydes with Allyl Acetates

Carbonyl allylation reactions constitute an important step in the formation of carbon-carbon reactions, and involve various related reactions that chiefly use allylmetal reagents. This report presents a nickel-catalyzed carbonyl allylation reaction using allyl acetate, which produces homoallyl alcohols in moderate to good yields, as an efficient methodology under reductive coupling conditions.

Photoredox Allylation Reactions Mediated by Bismuth in Aqueous Conditions

Organometallic allylic reagents are widely used in the construction of C?C bonds by Barbier-type reactions. In this communication, we have described a photoredox Barbier allylation of aldehydes mediated by bismuth, in absence of other metals as co-reductants. Mild reaction conditions, tolerance of oxygen, and use of aqueous solvent make this photoredox methodology attractive for green and sustainable synthesis of homoallylic alcohols.