611-95-0 Usage
Chemical Properties
white crystalline solid
Uses
Different sources of media describe the Uses of 611-95-0 differently. You can refer to the following data:
1. 4-Benzoylbenzoic acid,is a important organic intermediate. It can be used in agrochemical, pharmaceutical and dyestuff field etc.
2. 4-Benzoylbenzoic acid, along with methacrylic acid can be used as ligands for synthesizing a novel Tb(III) ternary complex with luminescent property.
General Description
4-Benzoylbenzoic acid is a benzophenone derivative. It can undergo hydrogenolysis to 4-benzylbenzoic acid. Cotton fabrics incorporated with 4-benzoylbenzoic acid have shown pesticide degradation ability, when exposed to UV irradiation.
Hazard
A poison.
Purification Methods
Dissolve the acid in hot H2O by adding enough aqueous KOH solution till distinctly alkaline, filter and then acidify with drops of conc HCl. Filter off, wash the solid with cold H2O, dry it at 100o, and recrystallise it from EtOH. [Wertheim J Am Chem Soc 55 2540 1933, Beilstein 10 H 753, 10 IV 3305.]
Check Digit Verification of cas no
The CAS Registry Mumber 611-95-0 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 6,1 and 1 respectively; the second part has 2 digits, 9 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 611-95:
(5*6)+(4*1)+(3*1)+(2*9)+(1*5)=60
60 % 10 = 0
So 611-95-0 is a valid CAS Registry Number.
InChI:InChI=1/C14H10O3/c15-13(10-4-2-1-3-5-10)11-6-8-12(9-7-11)14(16)17/h1-9H,(H,16,17)/p-1
611-95-0Relevant articles and documents
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Kleene
, p. 3523 (1940)
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Photoinduced Carbon Tetrabromide Initiated Aerobic Oxidation of Substituted Toluenes to Carboxylic Acids
Li, Xiaoqing,Xu, Xiangsheng,Yan, Xiaoyu,Yan, Xinhuan,Zhang, Guofu,Zheng, Kun
, p. 272 - 274 (2020/02/18)
A mild and metal-free procedure is reported for the aerobic oxidation of substituted toluenes to carboxylic acids by using CBr 4 as initiator under irradiation from a 400 nm blue light-emitting diode.
A Sunscreen-Based Photocage for Carbonyl Groups
Lineros-Rosa, Mauricio,Miranda, Miguel A.,Lhiaubet-Vallet, Virginie
, p. 7205 - 7211 (2020/05/08)
Photolabile protecting groups (PPGs) have been exploited in a wide range of chemical and biological applications, due to their ability to provide spatial and temporal control over light-triggered activation. In this work, we explore the concept of a new photocage compound based on the commercial UVA/UVB filter oxybenzone (OB; 2-hydroxy-4-methoxybenzophenone) for photoprotection and controlled release of carbonyl groups. The point here is that oxybenzone not only acts as a mere PPG, but also provides, once released, UV photoprotection to the carbonyl derivative. This design points to a possible therapeutic approach to reduce the severe photoadverse effects of drugs containing a carbonyl chromophore.
