6130-92-3

Basic information

• Product Name: 2,2,6,6-Tetramethyl-1-piperidinamine
• Synonyms: 2,2,6,6-Tetramethyl-1-piperidinamine
• CAS NO: 6130-92-3
• Molecular Formula: C₉H₂₀N₂
• Molecular Weight: 156.31
• Mol File: 6130-92-3.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 270.54°C (rough estimate)
• Flash Point: 37.5°C
• Appearance: /
• Density: 0.9494 (rough estimate)
• Vapor Pressure: 0.617mmHg at 25°C
• Refractive Index: 1.4820 (estimate)
• CAS DataBase Reference: 2,2,6,6-Tetramethyl-1-piperidinamine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2,6,6-Tetramethyl-1-piperidinamine(6130-92-3)
• EPA Substance Registry System: 2,2,6,6-Tetramethyl-1-piperidinamine(6130-92-3)

Safety Data

• Hazardous Substances Data: 6130-92-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H20N2/c1-8(2)6-5-7-9(3,4)11(8)10/h5-7,10H2,1-4H3

Upstream product

• 6130-93-4 2,2,6,6-tetramethyl-1-nitrosopiperidine 
• 768-66-1 2,2,6,6-tetramethyl-piperidine 

Downstream Products

• 57855-46-6 1-Methylenamino-2,2,6,6-tetramethyl-piperidin 
• 5557-98-2 2,6-dimethyl-2-heptene 
• 3074-78-0 2,6-dimethyl-1-heptene 
• 52688-89-8 1,1,2,2-tetramethylcyclopentane 
• 3073-66-3 1,1,3-trimethylcyclohexane 
• 42053-22-5 Bis-(2,2,6,6-tetramethyl-piperidin-1-yl)-diazene 
• 82281-71-8 [(meso-tetraphenylporphyrinato)][(2,2,6,6-tetramethyl-1-piperidyl)nitrene]iron(II) 
• 82281-71-8 Fe(C₆H₅)4C₂₀H₈N₄(N₂CH₂(CH₂C(CH₃)2)2) 

Relevant articles and documents

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Conformational Studies by Dynamic Nuclear Magnetic Resonance. Part 20. Internal Motion in Hydrazones and Related Derivatives

Restricted rotation about the N-N bond in unhindered, non-conjugated hydrazones (e.g.Me2N-N=CH2) has been detected by 13C n.m.r. below -150 degC.The results indicate that the N=C plane is coplanar with the dynamically averaged plane of the sp3 nitrogen, in contrast with hindered hydrazones (containing the 2,2,6,6-tetramethylpipridinyl ring, TMP) where the N=C moiety adopts a perpendicular conformation.Effects due to the slowing of ring reversal were not observed in hydrazones containing the TMP ring, but were detected in other hindered derivatives such as TMP-NH2 and TMP-NO.A most interesting feature becomes apparent in two hydrazones with the 2,6-cis-dimethylpiperidinyl (DMP) ring, DMP-N=CH2 and DMP-N=CHPh.In the same molecule the N=C moiety is coplanar with the averaged sp3 nitrogen plane when the methyls are axial, but perpendicular when the methyls are equatorial.