6130-93-4

Basic information

• Product Name: 2,2',6,6'-tetramethyl-N-nitrosopiperidine
• Synonyms: 2,2',6,6'-tetramethyl-N-nitrosopiperidine;1-Nitroso-2,2,6,6-tetramethylpiperidine;2,2,6,6-Tetramethyl-1-nitrosopiperidine
• CAS NO: 6130-93-4
• Molecular Formula: C₉H₁₈N₂O
• Molecular Weight: 170.29
• Mol File: 6130-93-4.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 299.91°C (rough estimate)
• Flash Point: 102.6°C
• Appearance: /
• Density: 1.0114 (rough estimate)
• Vapor Pressure: 0.0434mmHg at 25°C
• Refractive Index: 1.4790 (estimate)
• CAS DataBase Reference: 2,2',6,6'-tetramethyl-N-nitrosopiperidine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2',6,6'-tetramethyl-N-nitrosopiperidine(6130-93-4)
• EPA Substance Registry System: 2,2',6,6'-tetramethyl-N-nitrosopiperidine(6130-93-4)

Safety Data

• Hazardous Substances Data: 6130-93-4(Hazardous Substances Data)

Usage

Uses

2,?2'',?6,?6''-?Tetramethyl-?N-?nitrosopiperidine is a non-carcinogenic derivative of N-?nitrosopiperidine.

InChI:InChI=1/C9H18N2O/c1-8(2)6-5-7-9(3,4)11(8)10-12/h5-7H2,1-4H3

Upstream product

• 768-66-1 2,2,6,6-tetramethyl-piperidine 
• 2564-83-2 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical 
• 53256-22-7 ethyl β-anilinocinnamate 
• 75-52-5 nitromethane 
• 4424-17-3 2-aminobenzanilide 
• 1393481-89-4 1-(phenylethynyl)-2-(vinyloxy)-benzene 

Downstream Products

• 768-66-1 2,2,6,6-tetramethyl-piperidine 
• 6130-92-3 1-amino-2,2,6,6-tetramethylpiperidine 
• 85582-23-6 2,2,6,6-Tetramethyl-1-piperidin 
• 57855-46-6 1-Methylenamino-2,2,6,6-tetramethyl-piperidin 

Relevant articles and documents

Metal-free radical 5-exo-dig cyclizations of phenol-linked 1,6-enynes for the synthesis of carbonylated benzofurans

A new metal-free radical 5-exo-dig cyclization of phenol-linked 1,6-enynes with O2, 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO), and tBuONO is described. With this general method, carbonylated benzofurans can be accessed through incorporation

Potassium Iodide/tert-Butyl Hydroperoxide-Mediated Oxidative Annulation for the Selective Synthesis of N-Substituted 1,2,3-Benzotriazine-4(3H)-ones Using Nitromethane as the Nitrogen Synthon

A novel and efficient oxidative annulation of 2-aminobenzamides with nitromethane has been developed for the chemoselective synthesis of N-substituted 1,2,3-benzotriazine-4(3H)-ones in moderate to excellent yields under transition metal-free conditions. T

Reactions of trifluoroamine oxide: A route to acyclic and cyclic fluoroamines and N-nitrosoamines

Acyclic secondary fluoroamines and N-nitrosoamines R2NF and R2NNO (R = CH3, C2H5, n-C3H7, i-C3H7, n-C4H9, i-C4H9, c-C6H11) and saturated nonaromatic heterocyclic fluoroamines and N-nitrosoamines R NF and R NNO [R = c-C4H8, c-C5H10, 2,6-(CH3)2-c-C5H8, 2,2,6,6-(CH3)4-c-C5H6] were prepared by reacting trifluoroamine oxide (NF3O) with the respective amine at ≤0 °C in a 1:2 molar ratio. The amine hydrofluoride salts are also formed. Trifluoroamine oxide is a very effective fluorinating and nitrosating reagent and provides an excellent route to >NF- and >NNO-containing compounds. With PF5, 2,2,6,6-(CH3)4-c-C5H6NFgave [CH2CH2CH2C(CH3)2N +=C(CH3)2]PF6-.