61676-63-9

Basic information

• Product Name: 1,3,2-Benzodioxaborole, 2-(1-methylethoxy)-
• CAS NO: 61676-63-9
• Molecular Formula: C9H11BO3
• Molecular Weight: 177.996
• Mol File: 61676-63-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,3,2-Benzodioxaborole, 2-(1-methylethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,2-Benzodioxaborole, 2-(1-methylethoxy)-(61676-63-9)
• EPA Substance Registry System: 1,3,2-Benzodioxaborole, 2-(1-methylethoxy)-(61676-63-9)

Safety Data

• Hazardous Substances Data: 61676-63-9(Hazardous Substances Data)

Upstream product

• 32999-09-0 2-cyclohexylbenzo-[d][1,3,2]dioxaborole 
• 274-07-7 benzo[1,3,2]dioxaborole 

Downstream Products

• 84879-15-2 OC₆H₄OB(CH₃C₆H₄COCHCOCOOCH₃) 
• 105235-83-4 (OH)C₆H₄CHNNC(SCH₂C₆H₅)S(C₆H₄O₂B) 
• 107721-41-5 (C₆H₄O₂B)OC₆H₄CHNNC(SCH₂C₆H₅)S(C₆H₄O₂B) 
• 95099-30-2 OC₆H₄OBOC₆H₄CHNC₆H₄SO₂NHC₄H₃N₂ 
• 95099-48-2 OC₆H₄OBOC₆H₄CHNC₆H₄SO₂NHC₃H₂NS 
• 102815-58-7 (O)C₆H₄OBOC₆H₄CHNC₆H₄Br 
• 90963-58-9 C₆H₄(O)2BC₆H₄(OH)C(CH₃)NNCSNH₂ 
• 90963-55-6 C₆H₄(O)2BC₆H₄(OH)CHNNCSNH₂ 
• 102859-04-1 (O)C₆H₄OBOC₆H₄CHNC₆H₄Cl 
• 84879-16-3 OC₆H₄OB(C₆H₅COCHCOCOOCH₃) 
• 84879-14-1 OC₆H₄OB(BrC₆H₄COCHCOCOOCH₃) 
• 1565857-48-8 1-bromo-2-(catecholboryl)benzene 
• 90963-49-8 C₆H₄(O)2BC₆H₄(OH)C(CH₃)NNCONH₂ 
• 81767-23-9 C₆H₄O₂B(4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one) 

Relevant articles and documents

On titanium-promoted hydroborations of alkenes by borohydride and by catecholborane

Some literature reports of catalyzed hydroborations of alkenes by the borohydride anion and by catecholborane were investigated to probe the actual mode of hydroboration. Reactions involving both TiCl3 and Ti(OiPr)4 seems to involve predominantly formation of BH3 in situ, although there is some evidence that the metal may be directly involved in a few cases. Ambiguity arises because it is shown that alkyl boronate esters can be formed by exchange between catecholborane and alkylboranes, so formation of these esters is not firm evidence of catalysis.