61807-37-2

Basic information

• Product Name: Phenol, 4-iodo-, benzoate
• CAS NO: 61807-37-2
• Molecular Formula: C13H9IO2
• Molecular Weight: 324.118
• Mol File: 61807-37-2.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Phenol, 4-iodo-, benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 4-iodo-, benzoate(61807-37-2)
• EPA Substance Registry System: Phenol, 4-iodo-, benzoate(61807-37-2)

Safety Data

• Hazardous Substances Data: 61807-37-2(Hazardous Substances Data)

Upstream product

• 540-38-5 p-Iodophenol 
• 85909-02-0 N-benzyl-N-(tert-butoxycarbonyl)-benzamide 
• 64548-92-1 N-benzoyl-4-(N,N-dimethylamino)pyridinium chloride 
• 108-90-7 chlorobenzene 
• 100-52-7 benzaldehyde 
• 65-85-0 benzoic acid 
• 98-88-4 benzoyl chloride 
• 109731-85-3 benzoic acid-(4-dichloroiodanyl-phenyl ester) 
• 64-19-7 acetic acid 

Downstream Products

• 110144-67-7 4-benzoyloxy-trans-stilbene 
• 2714-93-4 4-fluorophenyl benzoate 
• 269409-70-3 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol 
• 1598431-99-2 4-(2,2,2-trifluoroethyl)phenyl benzoate 
• 1610943-14-0 C₂₀H₁₇IO₆S 
• 1613025-57-2 4-[(trimethylsilyl)ethynyl]phenyl benzoate 
• 1613025-55-0 4-[(4-nitrophenyl)buta-1,3-diyn-1-yl]phenyl benzoate 
• 1426919-96-1 4-[(4-nitrophenyl)buta-1,3-diyn-1-yl]phenol 
• 1613025-54-9 (E)-4-[6-(4-nitrophenyl)hexa-3-en-1,5-diyn-1-yl]phenol 
• 1613025-53-8 (E)-4-[6-(4-nitrophenyl)hexa-3-en-1,5-diyn-1-yl]phenyl benzoate 
• 3910-14-3 (4-ethynylphenyl)benzoate 
• 1613025-51-6 4-[3-cyclohexylidene-5-(4-nitrophenyl)penta-1,4-diyn-1-yl]phenyl benzoate 
• 1392011-57-2 1,3-dimethyl 2-(3-(4-(benzoyloxy)phenyl)prop-2-yn-1-yl)malonate 

Relevant articles and documents

Hydrogen-bond-assisted transition-metal-free catalytic transformation of amides to esters

The amide C-N cleavage has drawn a broad interest in synthetic chemistry, biological process and pharmaceutical industry. Transition-metal, luxury ligand or excess base were always vital to the transformation. Here, we developed a transition-metal-free hydrogen-bond-assisted esterification of amides with only catalytic amount of base. The proposed crucial role of hydrogen bonding for assisting esterification was supported by control experiments, density functional theory (DFT) calculations and kinetic studies. Besides broad substrate scopes and excellent functional groups tolerance, this base-catalyzed protocol complements the conventional transition-metal-catalyzed esterification of amides and provides a new pathway to catalytic cleavage of amide C-N bonds for organic synthesis and pharmaceutical industry. [Figure not available: see fulltext.]

Highly Active Manganese-Mediated Acylation of Alcohols with Acid Chlorides or Anhydrides

To explore further the practical uses of highly active manganese (Mn?), a variety of alcohols were treated with Mn?, and the resulting complexes were coupled with acid chlorides and/or acetic anhydride in the absence of any extra catalyst. The subsequent reactions took place smoothly under mild conditions, providing the corresponding O-acylation products in good to excellent isolated yields.