62572-86-5

Basic information

• Product Name: Ethanone, 1-(2,4-dinitrophenyl)-
• Synonyms: Ethanone, 1-(2,4-dinitrophenyl)-;2,4-Dinitro-phenylacetat;2,4-dinitroacetophenone;2.4-Dinitro-acetophenon
• CAS NO: 62572-86-5
• Molecular Formula: C8H6N2O5
• Molecular Weight: 210.146
• Mol File: 62572-86-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-(2,4-dinitrophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(2,4-dinitrophenyl)-(62572-86-5)
• EPA Substance Registry System: Ethanone, 1-(2,4-dinitrophenyl)-(62572-86-5)

Safety Data

• Hazardous Substances Data: 62572-86-5(Hazardous Substances Data)

Upstream product

• 1204-29-1 1-ethyl-2,4-dinitrobenzene 
• 1439930-79-6 (E)-1-(2,4-dinitrophenyl)ethanone O-methyl oxime 
• 80965-22-6 (E)-1-(4-nitrophenyl)ethan-1-one O-methyl oxime 
• 100-41-4 ethylbenzene 

Downstream Products

• 157640-14-7 6-amino-3-methyl-1,2-benzisoxazole 

Relevant articles and documents

Palladium-catalyzed chelation-assisted aromatic C-H nitration: Regiospecific synthesis of nitroarenes free from the effect of the orientation rules

A palladium-catalyzed chelation-assisted ortho-nitration of aryl C-H bond is described. A range of azaarenes such as 2-arylquinoxalines, pyridines, quinoline, and pyrazoles were nitrated with excellent chemo- and regioselectivity. Using the O-methyl oximyl group as a removable directing group, the regiospecific synthesis of a variety of o-nitro aryl ketones was achieved starting from aryl ketones via a three-step process involving the Pd-catalyzed ipso-nitration of C-H bond as a key step. Mechanistic investigations support a silver-mediated radical mechanism involving Pd((II/III) and/or Pd(II/IV) catalytic cycles under oxidizing conditions.