80965-22-6

Basic information

• Product Name: (E)-1-(4-nitrophenyl)ethan-1-one O-methyl oxime
• Synonyms: (E)-1-(4-nitrophenyl)ethan-1-one O-methyl oxime
• CAS NO: 80965-22-6
• Molecular Weight: 194.19
• Mol File: 80965-22-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (E)-1-(4-nitrophenyl)ethan-1-one O-methyl oxime(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-(4-nitrophenyl)ethan-1-one O-methyl oxime(80965-22-6)
• EPA Substance Registry System: (E)-1-(4-nitrophenyl)ethan-1-one O-methyl oxime(80965-22-6)

Safety Data

• Hazardous Substances Data: 80965-22-6(Hazardous Substances Data)

Upstream product

• 59862-56-5 4-nitroacetophenone oxime 
• 74-88-4 methyl iodide 
• 100-19-6 (4-nitrophenyl)ethanone 
• 593-56-6 N-methoxylamine hydrochloride 
• 80965-24-8 (Z)-p-nitroacetophenone O-methyloxime 

Downstream Products

• 80965-24-8 (Z)-p-nitroacetophenone O-methyloxime 
• 62572-86-5 1-(2,4-dinitrophenyl)ethanone 
• 1439930-79-6 (E)-1-(2,4-dinitrophenyl)ethanone O-methyl oxime 
• 4187-53-5 (S)-1-(p-nitrophenyl)ethylamine 

Relevant articles and documents

Use of Strain-Release for the Diastereoselective Construction of Quaternary Carbon Centers

Herein, we describe the formation of quaternary carbon centers with excellent diastereoselectivity via a strain-release protocol. An organometallic species is generated by Cp*Rh(III)-catalyzed C-H activation, which is then coupled with strained bicyclobut

Asymmetric reduction of oxime ethers promoted by chiral spiroborate esters with an O3BN framework

Enatioselective reduction of oxime ethers promoted by chiral spiroborate esters with an O3BN framework is reported for the first time. In the presence of (R,S)-1, 11 aralkyloxime ethers are reduced by borane-THF at 0-5 °C to give (S)-1-aralkylamine in high yield and excellent enatiomeric excess (up to 98% ee). Influence of reaction conditions on the enantioselectivity of the reduction is investigated, and a possible mechanism of the catalytic reduction is suggested.