62812-90-2

Basic information

• Product Name: (4-hydroxyphenyl)carbamodithioic acid - N,N-diethylethanamine (1:1)
• Synonyms: (4-Hydroxyphenyl)dithiocarbamicacid,triethylaminesalt
• CAS NO: 62812-90-2
• Molecular Formula: C₆H₁₅N*C₇H₇NOS₂
• Molecular Weight: 286.4566
• Mol File: 62812-90-2.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 317.7°C at 760 mmHg
• Flash Point: 145.9°C
• Vapor Pressure: 0.000203mmHg at 25°C
• CAS DataBase Reference: (4-hydroxyphenyl)carbamodithioic acid - N,N-diethylethanamine (1:1)(CAS DataBase Reference)
• NIST Chemistry Reference: (4-hydroxyphenyl)carbamodithioic acid - N,N-diethylethanamine (1:1)(62812-90-2)
• EPA Substance Registry System: (4-hydroxyphenyl)carbamodithioic acid - N,N-diethylethanamine (1:1)(62812-90-2)

Safety Data

• Hazardous Substances Data: 62812-90-2(Hazardous Substances Data)

Upstream product

• 75-15-0 carbon disulfide 
• 123-30-8 4-amino-phenol 
• 121-44-8 triethylamine 

Downstream Products

• 2131-60-4 4-hydroxyphenyl isothiocyanate 
• 61700-59-2 (4-hydroxyphenyl)cyanamide 
• 1520-27-0 1-(4-hydroxyphenyl)thiourea 

Relevant articles and documents

NIFUROXAZIDE ANALOGS AND THERAPEUTIC USES THEREOF

Nifuroxazide analogs, and their pharmaceutically acceptable salts and derivatives are described. Methods and uses are also provided that include the administration of an effective amount of the nifuroxazide analogs, or their pharmaceutically acceptable sa

Na2S2O8-mediated efficient synthesis of isothiocyanates from primary amines in water

We have developed two green, practical, and efficient procedures, including a one-pot one, to synthesize isothiocyanates from amines and carbon disulfide via desulfurization with sodium persulfate. Water is used as the solvent. Basic conditions are necessary for good chemoselectivity for isothiocyanates. Structurally diverse linear and branched alkyl amines and aryl amines are readily converted to isothiocyanates by the two procedures in satisfactory yields. Halogens, benzylic C-H bonds, methylthio, nitro, ester, alkenyl, electron-rich or -deficient (hetero)aryls, acetylenyl, and even phenolic and alcoholic hydroxyls are well tolerated. The one-pot procedure in water can also be used to realize the preparation of chiral isothiocyanates from chiral amines, and the modification of bioactive structures with free amino groups. In large-scale preparation, simple and practical purification procedures independent of column chromatography are developed.

A one-pot preparation of cyanamide from dithiocarbamate using molecular iodine

An efficient one-pot method for the synthesis of cyanamides from dithiocarbamate salts via a double desulfurization strategy using molecular iodine is disclosed. Dithiocarbamates, by the action of iodine yield isothiocyanates in situ, which on treatment with aqueous NH3 give thioureas. The thioureas so generated undergo further oxidative desulfurization with I2 giving corresponding cyanamides in good yields. Environmental benignity, cost effectiveness and high yields are the important attributes of this one pot procedure. The Royal Society of Chemistry 2009.