6345-94-4Relevant articles and documents
Photoinduced C(sp3)-H chlorination of amides with tetrabutyl ammonium chloride
Zhu, Yanshuo,Yu, Wei
supporting information, p. 10228 - 10232 (2021/12/13)
A new protocol was developed for the site-selective C(sp3)-H chlorination of amides with tetrabutyl ammonium chloride as the chlorinating agent. The reaction features a tandem sequence that involves a (diacetoxyiodo)benzene-mediated and chloride anion-involved N-H chlorination followed by photoinitiated chlorine atom transfer. A wide variety of carboxamides and sulfonamides were chlorinated at the δ-position by using this method.
DECONSTRUCTIVE FUNCTIONALIZATION METHODS AND COMPOUNDS
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Paragraph 0464-0470, (2020/01/31)
Disclosed herein, inter alia, are deconstructive functionalization methods and compounds made using the same.