63600-35-1

Basic information

• Product Name: ACETIC ACID 2-VINYLPHENYL ESTER
• Synonyms: 2-ACETOXYSTYRENE;2-VINYLPHENYL ACETATE;ACETIC ACID 2-VINYLPHENYL ESTER;Aceticacidvinylphenylester;aceticacid2-vinylphenylester(stabilizedwithphenothiazine)10900;ACETIC ACID 2-VINYLPHENYL ESTER, STABILIZED WITH PHENOTHIAZINE: 93%;2-Vinylphenyl Acetate (stabilized with Phenothiazine);Acetic Acid 2-Vinylphenyl Ester 2-Acetoxystyrene
• CAS NO: 63600-35-1
• Molecular Formula: C₁₀H₁₀O₂
• Molecular Weight: 162.19
• Mol File: 63600-35-1.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 246.752°C at 760 mmHg
• Flash Point: 94.497°C
• Appearance: /
• Density: 1.07
• Vapor Pressure: 0.027mmHg at 25°C
• Refractive Index: 1.5350-1.5390
• Storage Temp.: 0-10°C
• CAS DataBase Reference: ACETIC ACID 2-VINYLPHENYL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: ACETIC ACID 2-VINYLPHENYL ESTER(63600-35-1)
• EPA Substance Registry System: ACETIC ACID 2-VINYLPHENYL ESTER(63600-35-1)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• Hazardous Substances Data: 63600-35-1(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 117, p. 1151, 1995 DOI: 10.1021/ja00108a041

InChI:InChI=1/C10H10O2/c1-3-9-6-4-5-7-10(9)12-8(2)11/h3-7H,1H2,2H3

Upstream product

• 108-24-7 acetic anhydride 
• 695-84-1 2-allylphenol 
• 22412-89-1 cycloocta-2,4,6-trien-1-one 
• 74-86-2 acetylene 
• 108-95-2 phenol 
• 90-02-8 salicylaldehyde 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 75-36-5 acetyl chloride 

Downstream Products

• 2011-26-9 8-(2-acetoxy-phenyl)-7,10-diphenyl-8,9-dihydro-fluoranthene 
• 73444-61-8 Acetic acid 2-oxiranyl-phenyl ester 
• 24454-25-9 3-(2-hydroxyphenyl)propane-1,2-diol 
• 639820-74-9 ethyl (2-vinylphenoxy)acetate 
• 695-84-1 2-allylphenol 
• 59116-14-2 methyl 3-(2-acetoxyphenyl)propanoate 
• 1177259-18-5 (-)-(2S,3'S,4'R,6'R)-6'-(2-(tert-butyldiphenylsilyloxy)ethyl)-4'-(triisopropylsilyloxy)-3',4',5',6'-tetrahydrospiro[chroman-2,2'-pyran]-3'-ol 
• 1177259-09-4 (+)-(2R,3'R,4'S,6'R)-6'-(2-(tert-butyldiphenylsilyloxy)ethyl)-4'-(triisopropylsilyloxy)-3',4',5',6'-tetrahydrospiro[chroman-2,2'-pyran]-3'-ol 
• 1177259-00-5 (+)-2-(2-((2R,4R)-2-(2-(tert-butyldiphenylsilyloxy)ethyl)-4-(triisopropylsilyloxy)-3,4-dihydro-2H-pyran-6-yl)ethyl)phenol 
• 1177258-97-7 (-)-2-(2-((2R,4S)-2-(2-(tert-butyldiphenylsilyloxy)ethyl)-4-(triisopropylsilyloxy)-3,4-dihydro-2H-pyran-6-yl)ethyl)phenol 
• 1177259-33-4 (+)-(2R,3'S,4'R,6'R)-6'-(2-(tert-butyldiphenylsilyloxy)ethyl)-4'-(triisopropylsilyloxy)-3',4',5',6'-tetrahydrospiro[chroman-2,2'-pyran]-3'-ol 
• 1177259-27-6 (2S,3'R,4'S,6'R)-6'-(2-(tert-butyldiphenylsilyloxy)ethyl)-4'-(triisopropylsilyloxy)-3',4',5',6'-tetrahydrospiro[chroman-2,2'-pyran]-3'-ol 

Relevant articles and documents

HFIP Solvent Enables Alcohols to Act as Alkylating Agents in Stereoselective Heterocyclization

A new method for the stereoselective synthesis of highly functionalized oxygen heterocycles using allyl or benzyl alcohols as alkylating agents is presented. The process is efficient and atom economic, generating water as the only stoichiometric byproduct. Substoichiometric amounts of Ti(OiPr)4 in HFIP solvent are key to this reactivity, and the method tolerates a broad substitution pattern on both the alcohol initiator and homoallylic alcohol substrate. Preliminary mechanistic studies reveal in situ formation of a titanium complex with HFIP which may initiate the cyclization reaction. Further stereoselective functionalization of the products allows access to a diverse range of interesting heterocyclic structures.

Saccharinsulfonic acid: An efficient and recyclable catalyst for acetylation of alcohols, phenols, and amines

Saccharinsulfonic acid is an efficient catalyst of the protection of alcohols, phenols, and amines with acetic anhydride. All reactions were performed under mild and completely heterogeneous reaction conditions. with excellent yields.

Samarium trifluoromethanesulfonate: An efficient moisture tolerant acylation catalyst under solvent-free condition

Samarium trifluoromethanesulfonate catalyzed the acylation of phenols, alcohols, thiols, free reducing sugars, and glycosides in excellent yields at ambient temperature under solvent-free condition using stoichiometric amounts of various anhydrides. (Chemical Equation Presented). Copyright Taylor & Francis Group, LLC.