65578-58-7

Basic information

• Product Name: 1,2-Hydrazinedicarboxylic acid, 1-phenyl-, bis(1,1-dimethylethyl) ester
• CAS NO: 65578-58-7
• Molecular Formula: C16H24N2O4
• Molecular Weight: 308.378
• Mol File: 65578-58-7.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: 1,2-Hydrazinedicarboxylic acid, 1-phenyl-, bis(1,1-dimethylethyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Hydrazinedicarboxylic acid, 1-phenyl-, bis(1,1-dimethylethyl) ester(65578-58-7)
• EPA Substance Registry System: 1,2-Hydrazinedicarboxylic acid, 1-phenyl-, bis(1,1-dimethylethyl) ester(65578-58-7)

Safety Data

• Hazardous Substances Data: 65578-58-7(Hazardous Substances Data)

Upstream product

• 870-46-2 t-butoxycarbonylhydrazine 
• 98-80-6 phenylboronic acid 
• 16466-61-8 1,2-bis(t-butyloxycarbonyl)hydrazine 
• 870-50-8 di-tert-butyl (E)-azodicarboxylate 
• 870-50-8 di-tert-butyl-diazodicarboxylate 
• 24424-99-5 di-tert-butyl dicarbonate 
• 5123-13-7 5,5-dimethyl-2-phenyl-1,3,2-dioxaborinane 
• 780-69-8 triethoxyphenylsilane 
• 591-50-4 iodobenzene 
• 100-63-0 phenylhydrazine 
• 108-90-7 chlorobenzene 
• 108-86-1 bromobenzene 
• 42116-43-8 tert-butyl 2-phenylhydrazine-1-carboxylate 
• 312934-59-1 2,2-Bis(t-butyloxycarbonyl)-1-phenylhydrazine 

Downstream Products

• 828246-94-2 C₂₅H₃₂N₂O₆ 
• 3422-01-3 tert-butyl phenylcarbamate 
• 20488-61-3 trans-4-nitroazobenzene 
• 21650-49-7 (E)-1-(4-methoxyphenyl)-2-phenyldiazene 
• 875537-66-9 (E)-1-[4-(phenyldiazenyl)phenyl]ethanone 
• 6720-39-4 trans-phenyl-p-tolyl-diazene 
• 17082-12-1 trans-azobenzene 

Relevant articles and documents

A Modular Approach to Arylazo-1,2,3-triazole Photoswitches

Azoheteroarenes make up an emerging class of photoswitchable compounds with unique photophysical properties and advantages over traditional azobenzenes. Therefore, methods for synthesizing azoheteroarenes are highly desirable. Here, we utilize azide-alkyne click chemistry to access arylazo-1,2,3-triazoles, a previously unexplored class of azoheteroarenes that exhibit high thermal stabilities and near-quantitative bidirectional photoconversion. Controlling the catalyst or 1,3-dipole grants access to both regioisomeric arylazotriazoles and arylazoisoxazoles, highlighting the versatility of our approach.

Diaza [1,4] Wittig-type rearrangement of N-allylic-N-Boc-hydrazines into γ-amino- N -Boc-enamines

Diaza [1,4] Wittig-type rearrangement of N-allylic-N-Boc-hydrazines into γ-amino-N-Boc-enamines was demonstrated. The scope and limitation, experimental mechanistic studies, and a proposed reaction mechanism were also described.

Amination of Arylboronic Compounds via the Copper-Catalyzed Addition of Arylboronic Esters to Azodicarboxylates

Arylboronic esters add to di-tert-butyl azodicarboxylate under mild reaction conditions (at room temperature) to afford aryl-substituted hydrazine derivatives in good yields. The reaction tolerates a wide variety of functional groups.