6626-74-0Relevant articles and documents
Polymer phase-transition behavior driven by a charge-transfer interaction
Amemori, Shogo,Kokado, Kenta,Sada, Kazuki
, p. 4174 - 4178 (2013)
Cool down and get it together! The lower critical solution temperature (LCST) behavior of a polymer containing pyrene units was controlled by a charge-transfer (CT) interaction with an electron-accepting effector (see picture). The appearance of CT bands enabled quantitative evaluation of the thermodynamics of the association. Copyright
Origins of selectivity in a colorimetric charge-transfer sensor for diols
Rasberry, Roger D.,Smith, Mark D.,Shimizu, Ken D.
supporting information; experimental part, p. 2889 - 2892 (2009/05/11)
(Chemical Equation Presented) Bispyridyl hydrogen bonding receptor 1 forms colored charge transfer (CT) complexes with complementary phenols and naphthols. Despite its low association constants of ~101 M-1, receptor 1 was highly selective forming CT complexes of varying color and intensity with different diol guests. The selectivity of 1 was correlated with the ability of its CT band to simultaneously yield information about the association constant and the electronic structure of the phenols and naphthols.