66897-25-4

Basic information

• Product Name: 4-methoxy-N-(prop-2-en-1-yl)benzamide
• Synonyms: benzamide, 4-methoxy-N-2-propen-1-yl-; N-Allyl-4-methoxybenzamide
• CAS NO: 66897-25-4
• Molecular Formula: C₁₁H₁₃NO₂
• Molecular Weight: 191.2264
• Mol File: 66897-25-4.mol
• Article Data: 22

Chemical Properties

• Boiling Point: 348.9°C at 760 mmHg
• Flash Point: 164.8°C
• Density: 1.051g/cm³
• Vapor Pressure: 4.88E-05mmHg at 25°C
• Refractive Index: 1.522
• CAS DataBase Reference: 4-methoxy-N-(prop-2-en-1-yl)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methoxy-N-(prop-2-en-1-yl)benzamide(66897-25-4)
• EPA Substance Registry System: 4-methoxy-N-(prop-2-en-1-yl)benzamide(66897-25-4)

Safety Data

• Hazardous Substances Data: 66897-25-4(Hazardous Substances Data)

Upstream product

• 100-07-2 4-methoxy-benzoyl chloride 
• 107-11-9 1-amino-2-propene 
• 15226-74-1 dicobalt octacarbonyl 
• 104-93-8 p-methylanizole 
• 100-09-4 4-methoxybenzoic acid 
• 696-62-8 para-iodoanisole 
• 13939-06-5 molybdenum hexacarbonyl 
• 30364-57-9 4-methoxybenzoic acid 2,5-dioxo-1-pyrrolidinyl ester 

Downstream Products

• 99859-27-5 5-(bromomethyl)-2-(4-methoxyphenyl)-4,5-dihydrooxazole 
• 100126-18-9 4-methoxy-benzoic acid-(2,3-dibromo-propylamide) 
• 66896-89-7 N-Allyl-N-(4-methoxy-benzoyl)-benzenesulfonamide 
• 3424-93-9 4-methoxyphenylacetamide 
• 1433416-60-4 (2-(4-methoxyphenyl)-4,5-dihydrooxazol-5-yl)methyl acetate 
• 139583-91-8 2-methyl-4-methoxybenzamide 
• 214766-81-1 4-methoxy-N-methyl-N-(prop-2-en-1-yl)benzamide 
• 105-13-5 4-Methoxybenzyl alcohol 
• 23429-02-9 5-methyl-2-(4-methoxylphenyl)-4,5-dihydrooxazole 

Relevant articles and documents

Electrochemical oxidative cyclization of: N -allylcarboxamides: Efficient synthesis of halogenated oxazolines

Herein, we reported an efficient and sustainable intramolecular electrochemical cyclization of N-allylcarboxamides for the synthesis of various halogenated oxazolines. This method was conducted in a simple undivided cell by employing lithium halogen salts

Sequential catalytic carbonylation reactions for sustainable synthesis of biologically relevant entities

The sustainable synthesis of highly functionalised formylcarboxamide compounds with biological relevance is reported through a sequential aminocarbonylation/hydroformylation approach. The optimisation of palladium-catalysed aminocarbonylation of iodoaromatic substrates, using allylamine as nucleophile was first performed, with molybdenum hexacarbonyl as alternative CO source versus gaseous carbon monoxide. The combination of microwave irradiation with molybdenum hexacarbonyl allowed to selectively prepare a set of N-heterocyclic-based allylcarboxamides. Subsequent rhodium-catalysed hydroformylation of the allylcarboxamide intermediates led to the preparation of new pyridine, pyrazoline and chalcone derivatives containing both carboxamide and formyl moieties.

Electrochemical Chalcogenation of β,γ-Unsaturated Amides and Oximes to Corresponding Oxazolines and Isoxazolines

The current report represents a transition-metal-free synthesis of oxazoline and isoxazoline derivatives by a tandem electro-oxidative chalcogenation-cyclization process. Both C?Se and C?S bond-forming protocols were developed without using any external oxidant and the reaction was performed at room temperature, open to the air. Using this methodology, 29 substituted oxazoline and 16 substituted isoxazoline derivatives were synthesized with up to 91% isolated yield. (Figure presented.).