67106-77-8Relevant articles and documents
Kinetic Effects of Pressure on Thermal Z-E Isomerization of a Stilbazolium Betaine. Dependence of Activation Volume on Reaction Conditions
Asano, Tsutomu,Okada, Toshio
, p. 3606 - 3607 (1988)
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The aggregation of the merocyanine dyes, depending of the type of the counterions
Kolev, Tsonko,Koleva, Bojidarka B.,Stoyanov, Stanimir,Spiteller, Michael,Petkov, Ivan
experimental part, p. 1087 - 1096 (2009/02/02)
Counterions affect on the substructures formation in the case of the merocyanine dye, 1-methyl-4-[2-(4-hydroxyphenyl)ethenyl)]piridinium] hydrogensquarate both in gas and condense phase. Spectroscopically and structural elucidation of these aggregates have been performed, using solid-state conventional and linear-polarized IR-spectroscopy of oriented colloids as a nematic liquid crystal suspension, UV-vis spectroscopy, HPLC tandem ESI mass spectrometry, 1H and 13C NMR, TGV and DSC. Quantum chemical DFT calculations have been carried out as well. Experimental and theoretical data are compared with analogous ones of corresponding iodide salt of dye studied.
Thermal Cis-Trans Isomerization of Solvatochromic Merocyanines: Linear Correlations between Solvent Polarity and Adiabatic and Diabatic Transition Energies
Abdel-Halim, Shakir T.,Abdel-Kader, Mahmoud H.,Steiner, Ulrich E.
, p. 4324 - 4328 (2007/10/02)
The correlation between solvatochromy and the sovent-polarity-dependent rate constant kct of thermal cis-trans isomerization (solvatokinetic behavior) has been investigated for a stilbazolium-type merocyanine and an amphiphilic analogue in a polarity series of eight neat solvents (protic and aprotic).At room temperature kct varies over 7 orders of magnitude, decreasing with increasing solvent polarity.It has been demonstrated that the first transition energy ΔEmax and the free activation enthalpy ΔG(excit.)ct of thermal cis-trans isomerization are linearly correlated with each other and with Dimroth's solvent polarity parameter ET.These observations and the sovent-polarity-dependent increase of absorption band width are explained in terms of a model emphasizing the strong coupling between molecular conformation, electronic charge distribution, and solvent polarization.