69036-39-1

Basic information

• Product Name: Benzene, (1-octenylthio)-
• CAS NO: 69036-39-1
• Molecular Formula: C14H20S
• Molecular Weight: 220.379
• Mol File: 69036-39-1.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Benzene, (1-octenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (1-octenylthio)-(69036-39-1)
• EPA Substance Registry System: Benzene, (1-octenylthio)-(69036-39-1)

Safety Data

• Hazardous Substances Data: 69036-39-1(Hazardous Substances Data)

Upstream product

• 628-17-1 amyl iodide 
• 5296-64-0 allyl phenyl thioether 
• 111-71-7 heptanal 
• 629-05-0 n-octyne 
• 108-98-5 thiophenol 
• 52356-93-1 (Z)-1-octenyl iodide 
• 882-33-7 diphenyldisulfane 
• 42599-17-7 (E)-1-iodo-1-octene 
• 3561-67-9 bis(phenylthio)methane 
• 201230-82-2 carbon monoxide 
• 121410-98-8 O-<1,1-bis(phenylthio)methylheptyl> S-methyl dithiocarbonate 
• 5633-78-3 2-hexyl thiirane 
• 4661-46-5 2-carboxybenzene diazonium chloride 
• 69036-36-8 1,1-Bis-(phenylthio)-octan-2-ol 

Downstream Products

• 70004-05-6 (+/-)_S-(E)-1-(phenylsulfinyl)oct-1-ene 
• 512779-65-6 5-benzenesulfinyl-3-hexyl-1-(toluene-4-sulfonyl)-1H-indole 

Relevant articles and documents

A new oxapalladacycle generated via ortho C-H activation of phenylphosphinic acid: An efficient catalyst for Markovnikov-type additions of E-H bonds to alkynes

A new oxapalladacycle 3 can be conveniently prepared via direct ortho palladation of diphenylphosphinic acid with palladium acetate. Catalysts derived from 3 can efficiently catalyze Markovnikov-type additions of E-H bonds (P(O)-H, S-H and spC-H) to alkyn

Stereo-recognizing transformation of (E)-alkenyl halides into sulfides catalyzed by nickel(0) triethyl phosphite complex

(E)-Alkenyl halides were transformed into (E)-alkenyl sulfides by the nickel(0) triethyl phosphite complex-catalyzed reaction with thiols, whereas (Z)-alkenyl halides gave alkynes under the same reaction conditions. Aryl halides were also transformed into aryl sulfides using the same reagent system.

Rhodium-catalyzed highly selective thioformylation of acetylenes with thiols and carbon monoxide

Highly regioselective thioformylation of terminal acetylenes with thiols and carbon monoxide has been developed by the use of rhodium(I) complexes as the catalyst: formyl and thio groups are introduced into the terminal and inner positions of acetylenes, respectively. The thioformylation is performed in the presence of a catalytic amount of rhodium(I) complexes, such as RhH(CO)(PPh3)3, RhCl(PPh3)3, and RhCl(CO)(PPh3)2, under the pressure of CO (3 MPa) at 120°C in CH3CN to provide β-thio-α,β-unsaturated aldehydes in good yields. This thioformylation can be applied to a variety of terminal acetylenes and aromatic thiols. A mechanistic proposal includes the formation of the rhodium sulfide complex as the key species.