69300-13-6

Basic information

• Product Name: Cyclododecanecarbonitrile
• Synonyms: Cyclododecanecarbonitrile
• CAS NO: 69300-13-6
• Molecular Formula: C₁₃H₂₃N
• Molecular Weight: 0
• Mol File: 69300-13-6.mol
• Article Data: 8

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Cyclododecanecarbonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclododecanecarbonitrile(69300-13-6)
• EPA Substance Registry System: Cyclododecanecarbonitrile(69300-13-6)

Safety Data

• Hazardous Substances Data: 69300-13-6(Hazardous Substances Data)

Upstream product

• 151-50-8 potassium cyanide 
• 82201-16-9 cyclododecanone (2,4,6-triisopropylbenzenesulfonyl)hydrazone 
• 19158-51-1 P-toluenesulfonyl cyanide 
• 1501-82-2 cyclododecene 
• 294-62-2 cyclododecane 
• 557-21-1 zinc(II) cyanide 
• 103763-35-5 cyclododecyl methanesulfonate 
• 1724-39-6 cyclododecanol 
• 34039-83-3 chlorocyclododecane 
• 7795-35-9 cyclododecyl bromide 
• 557-21-1 dicyanozinc 
• 38622-91-2 [(p-methylphenyl)sulfonylmethyl]isonitrile 
• 830-13-7 cyclododecanone 
• 92030-75-6 Cyclododecancarbonsaeureamid 

Downstream Products

• 69300-19-2 (E)-cyclododec-1-ene-1-carbonitrile 
• 69300-14-7 3-cyclododecylpropanenitrile 
• 22047-01-4 3-Cyclododecyl-propionaldehyde 
• 5037-22-9 formyl cyclododecane 

Relevant articles and documents

Direct C(sp3)-H Cyanation Enabled by a Highly Active Decatungstate Photocatalyst

A highly efficient, direct C(sp3)-H cyanation was developed under mild photocatalytic conditions. The method enabled the direct cyanation of various C(sp3)-H substrates with excellent functional group tolerance. Notably, complex natural products and bioactive compounds were efficiently cyanated.

Preparation method of alkyl nitrile compound

The invention discloses a preparation method of an alkyl nitrile compound shown as formula I. The preparation method comprises the following step: in a solvent, in the presence of an additive and a catalyst, Zn (CN) 2 and an alkyl halide shown as formula II are subjected to a coupling reaction as shown in the specification to obtain the alkyl nitrile compound as shown in the formula I, wherein theadditive comprises an alkali, the catalyst comprises a nickel compound and a phosphine ligand; the nickel compound is one or more of zero-valent nickel, monovalent nickel salt and divalent nickel salt; when the nickel compound contains zero-valent nickel or divalent nickel salt, the catalyst further comprises a reducing agent. According to the preparation method disclosed by the invention, cyanation of an alkyl halide can be simply, conveniently and efficiently realized by using a cheap catalytic system, and the preparation method also has good functional group compatibility and substrate universality.

Deboronative cyanation of potassium alkyltrifluoroborates: Via photoredox catalysis

A photoredox catalytic method was developed for the direct cyanation of alkyltrifluoroborates. This reaction provides a new and useful transformation of the easily available alkyltrifluoroborates. The photocatalytic reaction can tolerate a variety of functional groups with mild reaction conditions. Mechanistic investigations are consistent with the present reaction following a radical pathway.