69924-97-6

Basic information

• Product Name: (+/-)-(αRS,1'SR,2'RS)-α-<(2'-hydroxy-2',6',6'-trimethylcyclohexyl)methyl>furan-3-methanol
• CAS NO: 69924-97-6
• Molecular Weight: 252.354
• Mol File: 69924-97-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (+/-)-(αRS,1'SR,2'RS)-α-<(2'-hydroxy-2',6',6'-trimethylcyclohexyl)methyl>furan-3-methanol(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-(αRS,1'SR,2'RS)-α-<(2'-hydroxy-2',6',6'-trimethylcyclohexyl)methyl>furan-3-methanol(69924-97-6)
• EPA Substance Registry System: (+/-)-(αRS,1'SR,2'RS)-α-<(2'-hydroxy-2',6',6'-trimethylcyclohexyl)methyl>furan-3-methanol(69924-97-6)

Safety Data

• Hazardous Substances Data: 69924-97-6(Hazardous Substances Data)

Upstream product

• 53101-93-2 3-furyllithium 
• 76215-61-7 trans-octahydro-4,4,7a-trimethylbenzofuran-2-ol 
• 69924-94-3 (+/-)-(R^*R^*)-α-<(2,2-dimethyl-6-methylenecyclohexyl)methyl>furan-3-methanol 
• 105426-84-4 2-(5',5'-dimethyl-1'-oxaspiro<2.5>octan-4'-yl)-1-(3-furyl)ethanone 
• 105426-83-3 2-(2',2'-dimethyl-6'-methylenecyclohexyl)1-(3-furyl)ethanone 
• 547-15-9 2-(6',6'-Dimethyl-2'-methylenecyclohexyl)ethanal 
• 76337-19-4 (3,3-Dimethylcyclohexenyl)methyl vinyl ether 
• 69924-96-5 (+/-)-(αRS,3'SR,4'RS)-α-(3-furyl)-5,5-dimethyl-1-oxaspiro<2.5>octane-4-ethanol 
• 69924-96-5 (+/-)-(αRS,3'RS,4'SR)-α-(3-furyl)-5,5-dimethyl-1-oxaspiro<2.5>octane-4-ethanol 
• 69924-97-6 (+/-)-(1'SR,2'SR)-α-<(2'-hydroxy-2',6',6'-trimethylcyclohexyl)methyl>furan-3-methanol 
• 37531-07-0 (+/-)-(3aα,7aβ)-4,4-7a-trimethyl-3a,4,5,6,7,7a-hexahydrobenzofuran-2(3H)-one 
• 90987-31-8 (+/-)-1-(3-furyl)-(2α-hydroxy-2,6,6-trimethylcyclohexyl)ethanone 
• 124177-08-8 ethyl (1R,3S)-3-(tert-butyldimethylsilyloxy)-2,2-dimethyl-6-methylenecyclohexaneacetate 
• 124177-08-8 ethyl (1R,3S)-3-(tert-butyldimethylsilyloxy)-2,2-dimethyl-6-methylenecyclohexaneacetate 

Downstream Products

• 69924-97-6 (+/-)-(αRS,1'SR,2'SR)-α-<(2'-hydroxy-2',6',6'-trimethylcyclohexyl)methyl>furan-3-methanol 
• 69924-97-6 (+/-)-(αRS,1'RS,2'RS)-α-<(2'-hydroxy-2',6',6'-trimethylcyclohexyl)methyl>furan-3-methanol 
• 90987-31-8 (+/-)-1-(3-furyl)-(2α-hydroxy-2,6,6-trimethylcyclohexyl)ethanone 

Relevant articles and documents

Stereoselective Synthesis of (+/-)-Ancistrofuran: Stereoselective Reduction of a γ-Hydroxyketone

A remarkably stereoselective reduction of a γ-hydroxyketone with two equiv. of lithium triethylborohydride has been observed and this effect has been suggested to originate from 'chelation control'; the reaction has been utilised in a short stereoselectiv

Stereoselective Synthesis of (+/-)-Ancistrofuran and its Stereoisomers

The four possible stereoisomers of ancistrofuran have been prepared from γ-cyclohomocitral.Addition of 3-furyl-lithium yielded two epimeric alcohols.Each alcohol was epoxidised with m-chloroperbenzoic acid and reduction with lithium aluminium hydride gave