71209-04-6Relevant articles and documents
SYNTHESES TOTALES ET ETUDES DE LIGNANES BIOLOGIQUEMENT ACTIFS. APPLICATION DE L'α-HYDROXYALKYLATION DE β-BENZYL γ-BUTYROLACTONES A LA CREATION DES SQUELETTES PHENYL TETRALINE ET BISBENZOCYCLOOCTADIENE - 4. SYNTHESE TOTALE DE LA (+/-)-STEGANONE ET DE SES C
Dhal, Robert,Brown, Eric,Robin, Jean-Pierre
, p. 2787 - 2794 (2007/10/02)
The biphenyl 16 (obtained from α-bromopiperonal and the aromatic iodide 14 by a modified Ullmann reaction) was cyclized by intramolecular hydroxyalkylation to the isomeric alcohols 17a and 17b.These were oxidized using Jones' reagent, to afford the enol 1
Asymmetric total synthesis of the antileukaemic lignan precursor (-)steganone and revision of its absolute configuration
Robin,Gringore,Brown
, p. 2709 - 2712 (2007/10/02)
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