7169-17-7

Basic information

• Product Name: Ethanone, 2-diazo-1-(2-methoxyphenyl)-
• CAS NO: 7169-17-7
• Molecular Formula: C9H8N2O2
• Molecular Weight: 176.175
• Mol File: 7169-17-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Ethanone, 2-diazo-1-(2-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 2-diazo-1-(2-methoxyphenyl)-(7169-17-7)
• EPA Substance Registry System: Ethanone, 2-diazo-1-(2-methoxyphenyl)-(7169-17-7)

Safety Data

• Hazardous Substances Data: 7169-17-7(Hazardous Substances Data)

Usage

General Description

Ethanone, 2-diazo-1-(2-methoxyphenyl)-, also known as 2-diazo-1-(2-methoxyphenyl)ethanone, is a diazo compound with the molecular formula C9H9N2O2. It is a yellow powder that is commonly used in the synthesis of various organic compounds and pharmaceuticals. This chemical is known for its diazo functionality, which makes it highly reactive and useful as a reagent in organic chemistry. It is important to handle this compound with caution due to its potential to form explosive diazoalkanes and diazoesters upon reaction with various nucleophiles. Additionally,

Upstream product

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• 186581-53-3 diazomethane 
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• 142472-15-9 1,3-bis(o-methoxyphenyl)-propane-1,3-dione 

Downstream Products

• 93209-95-1 2-amino-4-(2-methoxyphenyl)-1,3-thiazole 
• 28033-63-8 2-(2-methoxyphenyl)acetyl chloride 
• 124067-29-4 3-(2-anisyl)-α-diazo-2-propanone 
• 38694-34-7 1-chloro-3-(2-methoxyphenyl)propan-2-one 
• 271-89-6 1-benzofurane 
• 57329-30-3 3-(4'-chlorophenyl)benzofuran 
• 4687-24-5 benzofuran-3-carboxylic acid methyl ester 
• 33390-80-6 2-(2-methoxyphenyl)acetamide 
• 107637-99-0 3-hydroxybenzofuran 
• 93-25-4 2-methoxyphenylacetic acid 

Relevant articles and documents

Practical Application of the Aqueous 'Sulfonyl-Azide-Free' (SAFE) Diazo Transfer Protocol to Less α-C-H Acidic Ketones and Esters

The earlier described 'sulfonyl-Azide-free' ('SAFE') protocol for diazo transfer to CH-Acidic 1,3-dicarbonyl compounds (and their similarly activated congeners) has been extended to the less reactive monocarbonyl substrates, which previously required a se

An efficient PEG-400 mediated catalyst free green synthesis of 2-amino-thiazoles from α-diazoketones and thiourea

A simple and efficient method has been developed for the synthesis of 2-aminothiazoles from α-diazoketones using PEG-400 solvent system. This novel synthetic approach involves the reaction between thiourea and α-diazoketones in PEG-400 at 100 °C to yield the corresponding 2-aminothiazoles in good yields. The method is simple, rapid and generates thiazole derivatives in excellent yields without the use of any catalysts. This green protocol can be utilized for fast synthesis of various 2-aminothiazoles in good yields. [Figure not available: see fulltext.]

Palladium assisted substitution of 3-benzo[b]furan triflates

Triflates of 3-coumaranones were prepared, and experimented as coupling partners in palladium catalyzed Stille, Heck, Suzuki, and Sonogashira coupling reactions. The corresponding 3-substituted benzo[b]furans were obtained in excellent yields.