71690-15-8Relevant articles and documents
STEREOCHEMISTRY OF IMINO-GROUP REDUCTION. PART 6. STEREOCHEMISTRY OF REDUCTION OF 1,2-IMINO KETONES HAVING A PRE-EXISTING CHIRAL CENTRE. SYNTHESIS OF AMINO ALCOHOLS WITH THREE CHIRAL CENTRES
Alcaide, Benito,Dominguez, Gema,Lopez-Mardomingo, Carmen,Perez-Ossorio, Rafael,Plumet, Joaquin
, p. 99 - 104 (2007/10/02)
Stereochemical results of the lithium aluminium hydride and sodium borohydride reduction of 1,2-imino ketones, PhCOCPh=NCHRPh (R = Me, Et, Pr, Bu, i-Bu, i-Pr, t-Bu), are reported.The stereoselectivity is accounted for by competition between two possible r