71911-61-0

Basic information

• Product Name: diethyl (6-hydroxybicyclo[3.1.0]hex-6-yl)propanedioate
• CAS NO: 71911-61-0
• Molecular Formula: C₁₃H₂₀O₅
• Molecular Weight: 256.2949
• Mol File: 71911-61-0.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 334.5°C at 760 mmHg
• Flash Point: 118.7°C
• Density: 1.232g/cm³
• Vapor Pressure: 8.95E-06mmHg at 25°C
• Refractive Index: 1.519
• CAS DataBase Reference: diethyl (6-hydroxybicyclo[3.1.0]hex-6-yl)propanedioate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl (6-hydroxybicyclo[3.1.0]hex-6-yl)propanedioate(71911-61-0)
• EPA Substance Registry System: diethyl (6-hydroxybicyclo[3.1.0]hex-6-yl)propanedioate(71911-61-0)

Safety Data

• Hazardous Substances Data: 71911-61-0(Hazardous Substances Data)

Upstream product

• 81447-34-9 2-(tosyloxy)cyclohexanone 
• 105-53-3 diethyl malonate 
• 822-87-7 2-Chlorocyclohexanone 
• 685-87-0 Diethyl 2-bromomalonate 

Downstream Products

• 4039-31-0 3-[bis(ethoxycarbonyl)methyl]cyclohexanone 
• 63965-89-9 dimethyl 2-(2-oxocyclohexyl)malonate 
• 105-53-3 diethyl malonate 
• 24922-00-7 ethyl 3-cyclopentyl-3-oxopropionate 
• 6004-60-0 1-cyclopentylethanone 
• 3400-45-1 cyclopentanecarboxylic acid 

Relevant articles and documents

Reactivity of 2-chloro- and 2-(tosyloxy)cyclohexanones towards anions electrogenerated at carbonium and nitrogen atoms. Electrochemically induced Favorskii rearrangement

Carbonium and nitrogen anions were generated by cathodic reduction of 6, 7 and 8 or by deprotonation of 9 and 10 (by means of electrogenerated bases).Their reactivity towards α-substituted ketones 1 and 2 was studied.The reaction products 5b-d, 4b and 3 are formed according to the Favorskii rearrangement, substitution, and formal reduction mechanisms, respectively.In most cases, the reaction pathway appears to be driven by the applied electric potential.The Favorskii rearrangement undergone by 1 and 2 under electrochemical conditions can also be induced by nitrogen (Ph-NH--Ph) and carbonium (CH3COC-HCO2Et) anions, which have never been used before in this kind of reaction. - Keywords: probase / Favorskii rearrangement / electrogenerated anions / α-substituted cyclohexanones