72681-70-0

Basic information

• Product Name: L-Phenylalanine, N-(1,2-dioxopropyl)-, methyl ester
• CAS NO: 72681-70-0
• Molecular Formula: C13H15NO4
• Molecular Weight: 249.266
• Mol File: 72681-70-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: L-Phenylalanine, N-(1,2-dioxopropyl)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: L-Phenylalanine, N-(1,2-dioxopropyl)-, methyl ester(72681-70-0)
• EPA Substance Registry System: L-Phenylalanine, N-(1,2-dioxopropyl)-, methyl ester(72681-70-0)

Safety Data

• Hazardous Substances Data: 72681-70-0(Hazardous Substances Data)

Upstream product

• 72681-61-9 4-methyl-2,2-bis-trifluoromethyl-2H-oxazol-5-one 
• 7524-50-7 methyl (2S)-2-amino-3-phenylpropanoate hydrochloride 
• 67436-23-1 phenylalanine methyl ester tosylate 
• 5704-66-5 pyruvoyl chloride 

Downstream Products

• 79546-43-3 (S)-3-Phenyl-2-[(R)-2-(2,2,2-trifluoro-acetoxy)-propionylamino]-propionic acid methyl ester 
• 79546-50-2 (S)-3-Phenyl-2-[(S)-2-(2,2,2-trifluoro-acetoxy)-propionylamino]-propionic acid methyl ester 
• 79546-47-7 N-((S)-lactoyl)-(S)-phenylalanine methyl ester 
• 79546-37-5 (S)-2-((R)-2-Hydroxy-propionylamino)-3-phenyl-propionic acid methyl ester 
• 79546-37-5 (S)-2-(2-Hydroxy-propionylamino)-3-phenyl-propionic acid methyl ester 

Relevant articles and documents

SYNTHESIS OF CHIRAL DEPSIPEPTIDE BUILDING BLOCK BY THE ASYMMETRIC REDUCTION OF N-(α-KETOACYL)-α-AMINO ESTERS

Asymmetric reduction of N-(α-ketoacyl)-α-amino esters was performed by using homogeneous hydrosilylation and hydrogenation catalyzed by rhodium(I) complexes.The asymmetric hydrosilylation achieved good to high stereoselectivities giving the corresponding

SYNTHESIS OF CHIRAL OLIGOPEPTIDES BY MEANS OF CATALYTIC ASYMMETRIC HYDROGENATION OF DEHYDROPEPTIDES

Asymmetric hydrogenation of Ac-ΔTyr(Ac)-(S)-Ala-Gly-OMe (6), Ac-ΔTyr(Ac)-(R)-Ala-Gly-(S)-Phe-OMe (7), Ac-ΔPhe-NH-CH(R)-CH2-OCH2Ph (10), HCO-ΔPhe-(S)-Leu-OMe (16), X-AA-ΔPhe-AA'-OMe ( 5: X=tBOC, CBZ, CF3CO; AA, AA'= α-amino acid ), and t