79546-37-5Relevant articles and documents
Preparation of optically active peralkyldiphosphines and their use, as the rhodium(I) complex, in the asymmetric catalytic hydrogenation of ketones
Tani, Kazuhide,Suwa, Kenichi,Tanigawa, Eiji,Ise, Tomokazu,Yamagata, Tsuneaki,et al.
, p. 203 - 222 (2007/10/02)
Two types of the optically active peralkyldiphosphine, 2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(dialkylphosphino)butane (Rdiop 3) and N-(N'-substituted carbamoyl)-4-dicyclohexylphosphino-2-dicyclohexylphosphinomethylpyrrolidine (R-Cycapp 8), have been p
SYNTHESIS OF CHIRAL DEPSIPEPTIDE BUILDING BLOCK BY THE ASYMMETRIC REDUCTION OF N-(α-KETOACYL)-α-AMINO ESTERS
Ojima, Iwao,Tanaka, Toshiyuki,Kogure, Tetsuo
, p. 823 - 826 (2007/10/02)
Asymmetric reduction of N-(α-ketoacyl)-α-amino esters was performed by using homogeneous hydrosilylation and hydrogenation catalyzed by rhodium(I) complexes.The asymmetric hydrosilylation achieved good to high stereoselectivities giving the corresponding