729572-42-3

Basic information

• Product Name: 6-tosyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinolone
• Synonyms: 6-tosyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinolone
• CAS NO: 729572-42-3
• Molecular Weight: 375.491
• Mol File: 729572-42-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 6-tosyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinolone(CAS DataBase Reference)
• NIST Chemistry Reference: 6-tosyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinolone(729572-42-3)
• EPA Substance Registry System: 6-tosyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinolone(729572-42-3)

Safety Data

• Hazardous Substances Data: 729572-42-3(Hazardous Substances Data)

Upstream product

• 729572-39-8 6-benzenesulfonyl-2-methoxy-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinolin-1-ol 
• 98-59-9 p-toluenesulfonyl chloride 
• 51-67-2 tyrosamine 
• 259263-97-3 4-methyl-N-[2-(4-hydroxyphenyl)ethyl]benzenesulfonamide 
• 729572-41-2 6-tosyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinolin-1-yl trifluoromethanesulfonate 

Downstream Products

• 478-57-9 (+/-)-Aporphine 
• 519-01-7 5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinolone 

Relevant articles and documents

Synthesis of Aporphine Analogues via Palladium-Catalyzed Intramolecular Aryl-Aryl Dehydrogenative Coupling

Reported herein is an intramolecular dehydrogenative coupling of two inert aryl C-H bonds for the synthesis of aporphine analogues. The process represents a novel tool for the preparation of aporphines via palladiun-catalyzed C-H bond activation. The present reaction is compatible with various functional groups, and the coupling products have been further applied for the synthesis of natural products aporphine and zenkerine.