73194-30-6

Basic information

• Product Name: 1-(trifluoromethyl)-2-chloroethyl phenyl selenide
• Synonyms: 1-(trifluoromethyl)-2-chloroethyl phenyl selenide
• CAS NO: 73194-30-6
• Molecular Weight: 287.571
• Mol File: 73194-30-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(trifluoromethyl)-2-chloroethyl phenyl selenide(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(trifluoromethyl)-2-chloroethyl phenyl selenide(73194-30-6)
• EPA Substance Registry System: 1-(trifluoromethyl)-2-chloroethyl phenyl selenide(73194-30-6)

Safety Data

• Hazardous Substances Data: 73194-30-6(Hazardous Substances Data)

Upstream product

• 5707-04-0 Phenylselenyl chloride 
• 677-21-4 1,1,1-trifluoropropylene 

Downstream Products

• 73194-38-4 2-(3,3,3-Trifluoro-2-phenylselanyl-propyl)-malonic acid diethyl ester 
• 73194-39-5 2-(3,3-Difluoro-2-phenylselanyl-allyl)-malonic acid diethyl ester 
• 73194-37-3 2-Acetyl-5,5,5-trifluoro-4-phenylselanyl-pentanoic acid ethyl ester 
• 73194-35-1 6-Fluoro-2-methyl-5-phenylselanyl-4H-pyran-3-carboxylic acid ethyl ester 
• 28622-61-9 butyl phenyl selenide 
• 73194-32-8 1-(trifluoromethyl)ethenyl phenyl selenide 
• 73194-34-0 2-methoxy-(trifluoromethyl)ethyl phenyl selenide 

Relevant articles and documents

1-(Trifluoromethyl)ethenyl Phenyl Selenide and 1-(Trifluoromethyl)ethenyl Phenyl Sulfide

The title compounds were prepared by addition of phenylselenenyl chloride or phenylsulfenyl chloride to 3,3,3-trifluoropropene, followed by elimination of HCl.Both compounds react readily with nucleophiles, giving with ethyl acetoacetate novel 2-fluoro-4H-pyran derivatives.The selenium-substituted olefin reacted with n-butyllithium at selenium to give phenyl n-butyl selenide, while the corresponding sulfur-containig species underwent exclusive attack at the methylene terminus of the olefin.