7382-09-4

Basic information

• Product Name: cis-2,6-bis(phenylmethyl)cyclohexanone
• Synonyms: cis-2,6-bis(phenylmethyl)cyclohexanone
• CAS NO: 7382-09-4
• Molecular Weight: 278.394
• Mol File: 7382-09-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: cis-2,6-bis(phenylmethyl)cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: cis-2,6-bis(phenylmethyl)cyclohexanone(7382-09-4)
• EPA Substance Registry System: cis-2,6-bis(phenylmethyl)cyclohexanone(7382-09-4)

Safety Data

• Hazardous Substances Data: 7382-09-4(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 897-78-9 2,6-bis(phenylmethylene)cyclohexanone 
• 123-91-1 1,4-dioxane 
• 60-29-7 diethyl ether 
• 64-19-7 acetic acid 
• 67-56-1 methanol 
• 71-36-3 butan-1-ol 
• 7664-93-9 sulfuric acid 
• 3849-14-7 (+/-)-2t,6c-Dibenzyl-cyclohexanol 
• 7647-01-0 hydrogenchloride 
• 7382-09-4 (E)-2,6-Dibenzylcyclohexanone 
• 124-41-4 sodium methylate 
• 31021-04-2 2-benzyl-6-benzylidene-cyclohexanone 
• 555-31-7 aluminum isopropoxide 

Downstream Products

• 94961-40-7 (+/-)-trans-1.3-dibenzyl-cyclohexanone-⁽²⁾-semicarbazone 
• 7382-09-4 trans-1.3-Dibenzyl-cyclohexanon-⁽²⁾ 
• 3849-16-9 1r.3c-Dibenzyl-cyclohexanol-(2t) 
• 97156-81-5 2,2,6-tribenzyl-cyclohexanone 
• 7382-13-0 2,2,6,6-tetrabenzyl-cyclohexanone 
• 7382-09-4 (E)-2,6-Dibenzylcyclohexanone 
• 3849-14-7 (+/-)-2t,6c-Dibenzyl-cyclohexanol 

Relevant articles and documents

Alkylation of enolates with triflates.

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α-Benzylation of Ketones by Reaction with Benzylamine. Regioselective Reduction of C-C Double Bonds in Cohjugated Enones

Prolonged reaction of some ketones with benzylamine at reflux converts them into α-benzyl derivatives by a route involving Aldol condensation of the related ketimine with benzaldimine followed by exclusive reduction of the resultant C-C double bond.Reduction does not occur when pure benzylamine is used under oxygen-free nitrogen, however the inclusion of a trace of benzaldehyde restores the efficiency of the reaction.Treatment of several ketones in this manner established the scope of the process.When the reaction was extended to the reduction of α,β-unsaturated enones again using benzylamine, reaction times were shorter and the product yield greater.The possibility that the reductive step was an intramolecular 1,5-hydrogen transfer was studied.