7386-21-2Relevant articles and documents
Solvent-free, Efficient Transamidation of Carboxamides with Amines Catalyzed by Recyclable Sulfated Polyborate Catalyst
Mali, Anil S.,Indalkar, Krishna,Chaturbhuj, Ganesh U.
, p. 369 - 378 (2021/07/26)
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Visible-Light-Induced Metal-/Photocatalyst-Free C-H Bond Imidation of Arenes
Kuribara, Takahito,Nakajima, Masaya,Nemoto, Tetsuhiro
supporting information, p. 2235 - 2239 (2020/03/13)
In this study, a visible-light-induced intermolecular C-H bond imidation of arenes was achieved at ambient condition. By using simple phthalimide with (diacetoxyiodo)benzene and molecular iodine, direct metal-/photocatalyst-free C-N bond formation was achieved. The imidation protocol was designed by using time-dependent density functional theory calculations and experimentally demonstrated for 28 substrates with as high as 96% yield. Mechanistic studies indicated that radical-mediated aromatic substitution occurred via photolysis of N-iodophthalimide under visible-light irradiation.
Method for constructing N-(4-chlorophenyl)phthalimide in one step by using imine as starting material
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Paragraph 0022-0054, (2019/02/13)
The invention discloses a method for constructing N-(4-chlorophenyl)phthalimide in one step by using an imine as a starting material. (E)-N-(4-chlorophenyl)-1-phenylmethylenimine used as a reaction raw material undergoes a carbonylation reaction to form t