745831-92-9

Basic information

• Product Name: (R)-4-Benzyloxy-3-hydroxy-butyric acid (1R,2S)-1-(toluene-4-sulfonylamino)-indan-2-yl ester
• Synonyms: (R)-4-Benzyloxy-3-hydroxy-butyric acid (1R,2S)-1-(toluene-4-sulfonylamino)-indan-2-yl ester
• CAS NO: 745831-92-9
• Molecular Weight: 495.596
• Mol File: 745831-92-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-4-Benzyloxy-3-hydroxy-butyric acid (1R,2S)-1-(toluene-4-sulfonylamino)-indan-2-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-4-Benzyloxy-3-hydroxy-butyric acid (1R,2S)-1-(toluene-4-sulfonylamino)-indan-2-yl ester(745831-92-9)
• EPA Substance Registry System: (R)-4-Benzyloxy-3-hydroxy-butyric acid (1R,2S)-1-(toluene-4-sulfonylamino)-indan-2-yl ester(745831-92-9)

Safety Data

• Hazardous Substances Data: 745831-92-9(Hazardous Substances Data)

Upstream product

• 175523-35-0 (+)-(1R,2S)-1-(N-tosylamino)-2-indanol 
• 745831-83-8 Chloro-acetic acid (1R,2S)-1-(toluene-4-sulfonylamino)-indan-2-yl ester 
• 60656-87-3 benzyloxyacetoaldehyde 

Downstream Products

• 81096-93-7 (R)-1-O-benzyl-1,2,4-butanetriol 

Relevant articles and documents

Stereoselective chloroacetate aldol reactions: Syntheses of acetate aldol equivalents and darzens glycidic esters

Aldol reaction of the Ti-enolate derived from cis-1-tosylamido-2-indanyl chloroacetate with representative aldehydes proceeded in excellent yield and high diastereoselectivities. Removal of chlorine provided alternative access to highly diastereoselective acetate aldol equivalents or the corresponding glycidic ester condensation products.