76346-07-1

Basic information

• Product Name: Benzene, 1,1'-(3-methyl-1-propene-1,3-diyl)bis[4-nitro-, (E)-
• CAS NO: 76346-07-1
• Molecular Formula: C16H14N2O4
• Molecular Weight: 298.298
• Mol File: 76346-07-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(3-methyl-1-propene-1,3-diyl)bis[4-nitro-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(3-methyl-1-propene-1,3-diyl)bis[4-nitro-, (E)-(76346-07-1)
• EPA Substance Registry System: Benzene, 1,1'-(3-methyl-1-propene-1,3-diyl)bis[4-nitro-, (E)-(76346-07-1)

Safety Data

• Hazardous Substances Data: 76346-07-1(Hazardous Substances Data)

Upstream product

• 6531-13-1 1-[4-nitrophenyl]-1-ethanol 
• 16793-35-4 1,2-dibromo-1,3-diphenyl-butane 
• 76346-08-2 1,2-dibromo-1,3-bis(4-nitrophenyl)butane 

Downstream Products

• 108-88-3 toluene 
• 71-43-2 benzene 
• 7302-00-3 (E)-1,3-diphenyl-1-butene 
• 7302-01-4 (Z)-(3-methyl-1-propene-1,3-diyl)dibenzene 
• 142-82-5 n-heptane 
• 30611-16-6 2-(4-nitrophenyl)propionaldehyde 
• 555-16-8 4-nitrobenzaldehdye 
• 100-19-6 (4-nitrophenyl)ethanone 
• 300-57-2 allylbenzene 
• 873-49-4 cyclopropylbenzene 
• 76346-09-3 cis-1,3-bis(4-nitrophenyl)-1-butene 

Relevant articles and documents

Iron-catalyzed stereospecific olefin synthesis by direct coupling of alcohols and alkenes with alcohols

Chemical equations presented. An efficient Fe(III)-catalyzed direct coupling of alkenes with alcohols and cross-coupling of alcohols with alcohols to give the corresponding substituted (E)-alkenes stereospecifically is demonstrated. Additionally, this reaction could be scaled up. The kinetic isotope effect (KIE) experiments indicated a typical secondary isotope effect in this process. Although benzylic alcohols were effective substrates, mild conditions, atom efficiency, environmental soundness, and stereospecificity are features that make this procedure very attractive.