7642-42-4

Basic information

• Product Name: (E)-1-phenylprop-1-en-1-yl acetate
• Synonyms: (E)-1-phenylprop-1-en-1-yl acetate
• CAS NO: 7642-42-4
• Molecular Weight: 176.215
• Mol File: 7642-42-4.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: (E)-1-phenylprop-1-en-1-yl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-phenylprop-1-en-1-yl acetate(7642-42-4)
• EPA Substance Registry System: (E)-1-phenylprop-1-en-1-yl acetate(7642-42-4)

Safety Data

• Hazardous Substances Data: 7642-42-4(Hazardous Substances Data)

Upstream product

• 673-32-5 1-Phenylprop-1-yne 
• 1600-27-7 mercury(II) diacetate 
• 108-22-5 Isopropenyl acetate 
• 93-55-0 1-phenyl-propan-1-one 
• 108-24-7 acetic anhydride 
• 64-19-7 acetic acid 
• 83808-03-1 1-phenylpropyl acetate 

Relevant articles and documents

Rh-catalyzed asymmetric hydrogenation of α-aryl-β-alkylvinyl esters with chiral ferrocenylphosphine-phosphoramidite ligand

An enantioselective Rh-catalyzed hydrogenation of E/Z mixtures of trisubstituted vinyl esters has been disclosed. With a combination of [Rh(COD)2]BF4 and a structurally fine-tuning chiral ferrocenylphosphine-phosphoramidite ligand as the catalyst, a variety of E/Z mixtures of α-aryl-β-alkylvinyl esters have been successfully hydrogenated in high yields and with good to high enantioselectivities (up to 96% ee). The presence of a small amount of tBuOH proved to be beneficial to improve the hydrogenation outcome.

Visible light induced C-H monofluoroalkylation to synthesize 1,4-unsaturated compound

We developed a method to synthesize fluorinated 1,4-unsaturated dicarbonyl compounds via photoredox catalyzed radical addition process. Commercially available ethyl bromodifluoroacetate (BrCF2CO2Et) as fluoroalkyl source, the corresponding fluoro-containing dicarbonyl compounds could be obtained in moderate to good yields.

Homolytic carbostannylation of alkenes and alkynes with tributylstannyl enolates

matrix presented In the presence of AIBN, tributylstannyl enolates derived from aromatic ketones reacted with electron-deficient alkenes and a variety of alkynes to give the corresponding carbostannylated adducts. The reactions with methyl acrylate gave α-tributylstannylmethyl-γ-ketoesters, unlike the known Michael-type reaction of stannyl enolates forming δ-ketoesters. The carbostannylation of alkynes proceeded in an anti addition mode to afford β,γ-unsaturated ketones. The reactivity of stannyl enolates as radical transfer agents could be utilized for radical cyclization of 1,6-enynes.