79128-08-8Relevant articles and documents
Probing the salt-metathesis route to bis(aryl)calcium compounds: Structure of an arylcalcate complex
Harder, Sjoerd,Ruspic, Christian
, p. 5743 - 5750 (2015)
1,3-Diisopropoxybenzene can be selectively metalated by nBuLi or by the superbase mixtures nBuLi/NaOC(Me)2Et or nBuLi/KOC(Me)2Et to give 2,6-diisopropoxyphenyllithium (71 %), 2,6-diisopropoxyphenylsodium (61 %), or 2,6-diisopropoxyph
Barbier–Negishi Coupling of Secondary Alkyl Bromides with Aryl and Alkenyl Triflates and Nonaflates
Zhang, Ke-Feng,Christoffel, Fadri,Baudoin, Olivier
supporting information, p. 1982 - 1986 (2018/02/06)
A mild and practical Barbier–Negishi coupling of secondary alkyl bromides with aryl and alkenyl triflates and nonaflates has been developed. This challenging reaction was enabled by the use of a very bulky imidazole-based phosphine ligand, which resulted in good yields as well as good chemo- and site selectivities for a broad range of substrates at room temperature and under non-aqueous conditions. This reaction was extended to primary alkyl bromides by using an analogous pyrazole-based ligand.
Α-olefin complexes and using the same, and (meth) acrylic acid ester copolymer
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Paragraph 0085; 0086; 0087, (2017/01/05)
PROBLEM TO BE SOLVED: To provide a catalyst component for producing polymer having high molecular weight, and a method of producing α-olefin (meth)acrylic ester copolymer using the same.SOLUTION: There are provided the metal complex represented by general