794458-05-2

Basic information

• Product Name: 1,2-Acenaphthylenediamine, N,N'-bis[2,6-bis(1-methylethyl)phenyl]-
• CAS NO: 794458-05-2
• Molecular Formula: C36H42N2
• Molecular Weight: 502.743
• Mol File: 794458-05-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,2-Acenaphthylenediamine, N,N'-bis[2,6-bis(1-methylethyl)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Acenaphthylenediamine, N,N'-bis[2,6-bis(1-methylethyl)phenyl]-(794458-05-2)
• EPA Substance Registry System: 1,2-Acenaphthylenediamine, N,N'-bis[2,6-bis(1-methylethyl)phenyl]-(794458-05-2)

Safety Data

• Hazardous Substances Data: 794458-05-2(Hazardous Substances Data)

Usage

Category

Acenaphthylene derivative

Structure

Two acenaphthylene rings connected by a diamine linker

Function

a. Used in the synthesis of novel materials and pharmaceuticals
b. Acts as a ligand for the synthesis of coordination complexes
c. Investigated for potential biological activities and applications in medicinal chemistry

Application

Varies depending on specific application and formulation

Notable Feature

Complex chemical compound

Importance

Useful in coordination chemistry and potential applications in medicinal chemistry

Caution

Exact properties and uses may vary depending on application and formulation

Upstream product

• 24544-04-5 2,6-diisopropylbenzenamine 
• 82-86-0 acenaphthene quinone 
• 153625-67-3 1,2-bis-[(2,6-diisopropylphenyl)imino]acenaphthene 

Downstream Products

• 733810-42-9 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene germanium 
• 1206688-26-7 Th(1,2-bis(2,6-diisopropylphenylimino)acenaphthylene^(2-))2(THF) 
• 1220882-44-9 [(SBz)2Ga(1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene(-2H))] 

Relevant articles and documents

Chromium and tungsten complexes with a paramagnetic gallaimidazole ligand

The reaction of digallane [(dpp-bian)Ga—Ga(dpp-bian)] (1) (dpp-bian is 1,2-bis[(2,6-di-isopropylphenyl)imino]acenaphthene dianion) with chromium or tungsten hexacarbonyl affords the complexes [(dpp-bian)Ga—Cr(CO)5] (2) and [(dpp-bian)Ga—W(CO)5] (3), respectively, containing the neutral radical [(dpp-bian)Ga:]. In both cases, temperature-dependent solvation of the gallium center was observed in a tetrahydrofuran solution. The recrystallization of compound 2 from pyridine gave the new complex [(dpp-bian)(Py)Ga—Cr(CO)5] (4). New compounds 2–4 were characterized by EPR and IR spectroscopy and elemental analysis. The molecular structures of complexes 2–4 were established by single-crystal X-ray diffraction.

Novel yttrium and zirconium catalysts featuring reduced Ar-BIANH2 ligands for olefin hydroamination (Ar-BIANH2 = bis-arylaminoacenaphthylene)

The novel class of bis-arylaminoacenaphthylenes (Ar-BIANH2) was employed for the preparation of zirconium and yttrium complexes to be used as catalysts for cyclohydroamination of a number of primary and secondary aminoalkenes. The complex [(2,6