79641-99-9Relevant articles and documents
Formation of 6-Azaindoles by Intramolecular Diels-Alder Reaction of Oxazoles and Total Synthesis of Marinoquinoline A
Jhaveri, Dishit P.,Osano, Mana,Wipf, Peter
supporting information, p. 2215 - 2219 (2020/04/09)
A new variant of the intramolecular Diels-Alder oxazole (IMDAO) cycloaddition that provides direct access to 6-azaindoles was developed. The IMDAO reaction was applied in a total synthesis of the aminophenylpyrrole-derived alkaloid marinoquinoline A, also
SYNTHESIS OF (+/-)-JATROPHAM, AN ANTITUMOR ALKALOID FROM JATROPHA MACRORHIZA
Yakushijin, Kenichi,Suzuki, Rika,Hattori, Ren,Furukawa, Hiroshi
, p. 1157 - 1160 (2007/10/02)
The synthesis of jatropham, assigned as 5-hydroxy-3-methyl-3-pyrrolin-2-one 4, and of its 4-methyl isomer 14 is achieved utilizing an autoxidation of 2-furylcarbamates 2 and 11 as the key step.