80006-88-8Relevant articles and documents
Sulfonamidoquinoline/palladium(II)-dimer complex as a catalyst precursor for palladium-catalyzed γ-Selective and stereospecific allyl-aryl coupling reaction between allylic acetates and arylboronic acids
Makida, Yusuke,Ohmiya, Hirohisa,Sawamura, Masaya
supporting information; experimental part, p. 410 - 414 (2011/10/03)
On neutral territory: A neutral palladium(II)-dimer catalyst system incorporating anionic sulfonamidoquinoline ligands is effective for the γ-selective and stereospecific allyl-aryl coupling between acyclic (E)-allylic acetates and arylboronic acids. Copy
Copper-catalyzed substitution reactions of acylal with organomanganese reagents
Deshmukh, Madhukar B.,Jadhav, Sunil D.,Kadam, Shashikant V.
, p. 989 - 994 (2008/09/18)
A mild method for the copper-catalyzed substitution of aldehyde acylals with organomanganese reagents is reported. This operationally simple C-C bond-forming protocol uses different Cu(I) catalysts. Acylal from trans-cinnamaldehyde furnishes conjugated addition product when reacted with alkyl and aryl organomanganese reagents in presence of 10 mol % of Cu(NCMe) 2 (PPh3)2[BF4] and 2 equivalent of Me3Si-C1 as an accelerator. This reagent can be efficiently used in the substitution of one acetate group of aromatic acylal to form esters in high yield.