80532-35-0

Basic information

• Product Name: (2Z)-3-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]prop-2-en-1-ol
• Synonyms: (2Z)-3-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]prop-2-en-1-ol
• CAS NO: 80532-35-0
• Molecular Weight: 158.197
• Mol File: 80532-35-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2Z)-3-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]prop-2-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (2Z)-3-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]prop-2-en-1-ol(80532-35-0)
• EPA Substance Registry System: (2Z)-3-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]prop-2-en-1-ol(80532-35-0)

Safety Data

• Hazardous Substances Data: 80532-35-0(Hazardous Substances Data)

Upstream product

• 36326-38-2 3-<(4'S)-2',2'-dimethyl-1',3'-dioxolan-4'-yl>prop-2-enoic acid ethyl ester 

Downstream Products

• 578731-32-5 (2S,3Z)-1,2-dihydroxy-1,2-O-isopropylidene-5-(4-methoxyphenylthio)-3-pentene 
• 88367-63-9 (1S,2S)-3-(tert-Butyl-diphenyl-silanyloxy)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-propane-1,2-diol 
• 88367-63-9 (1S,2S)-3-(tert-Butyl-diphenyl-silanyloxy)-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-propane-1,2-diol 
• 3673-15-2 (4S,5S,4'S)-2,2,2',2'-Tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-carbaldehyde 
• 3969-86-6 1,2:3,4-Di-O-isopropylidene-DL-ribitol 
• 488-81-3 Adonitol 
• 128373-69-3 (2S),(Z)-5-benzyloxy-1-tosyloxy-3-penten-2-ol 
• 128373-67-1 (2S),(Z)-5-benzyloxy-3-pentene-1,2-diol 
• 128442-96-6 (2S),(Z)-5-benzyloxy-1,2-epoxy-3-pentene 
• 118276-34-9 (3S,4'S)-3-(2,2-dimethyl-1,3-dioxolan-4-yl)-4-(phenylthio)-1-butene 
• 219926-67-7 (2E,4E)-5-Phenylsulfonylpenta-2,4-dien-1-ol 
• 153861-48-4 (1R,2S,4'S)-2-<<(tert-Butyldiphenylsilyl)oxy>methyl>-1-(2',2'-dimethyl-1',3'-dioxolan-4'-yl)cyclopropane 
• 331005-81-3 ethyl 2-acetoxy-3,4-dihydroxy-6-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]-(1R,2R,3R,4R,6R)-cyclohexane-1-carboxylate 
• 331005-80-2 ethyl 2-acetoxy-3,4-dihydroxy-6-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]-(1S,2R,3R,4R,6R)-cyclohexane-1-carboxylate 

Relevant articles and documents

Synthesis of diastereomerically and enantiomerically pure 2,3-disubstituted tetrahydrofurans using a sulfoxonium ylide

Nucleophilic substitution reactions of 2,3-epoxy alcohols, easily prepared via Sharpless asymmetric epoxidation chemistry, offer access to a wide variety of enantiomerically pure compounds. In this communication, we describe the use of a Payne rearrangement to control regioselectivity in the ring-opening of a series of 2,3-epoxy alcohols with dimethylsulfoxonium methylide to yield diastereomerically and/or enantiomerically pure disubstituted tetrahydrofuran rings. The factors influencing the success and substitution pattern of the THF ring products are discussed, including steric, electronic, and solvent effects. Copyright