80921-74-0Relevant articles and documents
Gold-catalyzed cycloisomerization of [3]-cumulenols
Ferrand, Laura,Das Neves, Nicolas,Malacria, Max,Mouriès-Mansuy, Virginie,Ollivier, Cyril,Fensterbank, Louis
, p. 53 - 57 (2015/03/30)
The gold-catalyzed cycloisomerization of tetrasubstituted [3]-cumulenols has been investigated. Overall, two main pathways are followed. In the presence of gold(III) catalysts, a dehydration process prevails giving diastereomerically pure dienynes while g
