80965-21-5

Basic information

• Product Name: (E)-1-(4-methoxyphenyl)ethan-1-one O-methyl oxime
• Synonyms: (E)-1-(4-methoxyphenyl)ethan-1-one O-methyl oxime
• CAS NO: 80965-21-5
• Molecular Weight: 179.219
• Mol File: 80965-21-5.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: (E)-1-(4-methoxyphenyl)ethan-1-one O-methyl oxime(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-(4-methoxyphenyl)ethan-1-one O-methyl oxime(80965-21-5)
• EPA Substance Registry System: (E)-1-(4-methoxyphenyl)ethan-1-one O-methyl oxime(80965-21-5)

Safety Data

• Hazardous Substances Data: 80965-21-5(Hazardous Substances Data)

Upstream product

• 80965-23-7 (Z)-p-methoxyacetophenone O-methyloxime 
• 593-56-6 N-methoxylamine hydrochloride 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 2475-92-5 (E)-1-(4-methoxyphenyl)ethanone oxime 
• 74-88-4 methyl iodide 

Downstream Products

• 2475-92-5 4-methoxyacetophenone oxime 
• 80965-23-7 (Z)-p-methoxyacetophenone O-methyloxime 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 1352619-35-2 C₁₄H₂₀N₂O₃ 
• 1401733-63-8 (5-methoxy-2-(1-(methoxyimino)ethyl)phenyl)(phenyl)methanone 
• 6298-96-0 1(R)-(4-methoxyphenyl)-ethylamine 
• 6298-96-0 (S)-1-(4-methoxyphenyl)ethylamine 

Relevant articles and documents

Access to Branched Allylarenes via Rhodium(III)-Catalyzed C-H Allylation of (Hetero)arenes with 2-Methylidenetrimethylene Carbonate

A rhodium(III)-catalyzed C-H allylation of (hetero)arenes by using 2-methylidenetrimethylene carbonate as an efficient allylic source has been developed for the first time. Five different directing groups including oxime, N-nitroso, purine, pyridine, and pyrimidine were compatible, delivering various branched allylarenes bearing an allylic hydroxyl group in moderate to excellent yields.

Nitrate promoted mild and versatile Pd-catalysed C(sp2)-H oxidation with carboxylic acids

A nitrate-promoted Pd-catalysed mild cross-dehydrogenative C(sp2)-H bond oxidation of oximes or azobenzenes with diverse carboxylic acids has been developed. In contrast to the previous catalytic systems, this protocol features mild conditions (close to room temperature for most cases) and a broad substrate scope (up to 64 examples), thus constituting a versatile method to directly prepare diverse O-aryl esters. Moreover, the superiority of the nitrate additive in this mild transformation was further determined by experimental and computational evidence.

Palladium-Catalyzed C(sp2)-H Acetoxylation via Electrochemical Oxidation

Palladium-catalyzed arene C(sp2)-H acetoxylation has emerged as a powerful tool to construct a carbon-oxygen (C-O) bond. However, the requirement of stoichiometric chemical oxidants for this transformation possesses a significant disadvantage.