81693-79-0

Basic information

• Product Name: Benzene, 1-hexyl-2-methoxy-
• CAS NO: 81693-79-0
• Molecular Formula: C13H20O
• Molecular Weight: 192.301
• Mol File: 81693-79-0.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzene, 1-hexyl-2-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-hexyl-2-methoxy-(81693-79-0)
• EPA Substance Registry System: Benzene, 1-hexyl-2-methoxy-(81693-79-0)

Safety Data

• Hazardous Substances Data: 81693-79-0(Hazardous Substances Data)

Upstream product

• 529-28-2 4-iodoanisol 
• 85630-19-9 N,N-diethyl-1-carbamyloxy-2-methoxybenzene 
• 44767-62-6 n-hexylmagnesium chloride 
• 1137-57-1 2-methoxyphenyl N,N-dimethylsulfamate 
• 135-02-4 ortho-anisaldehyde 
• 21406-61-1 pentyltriphenylphosphonium bromide 
• 592-41-6 1-hexene 
• 544-10-5 1-Chlorohexane 
• 16750-63-3 2-methoxyphenylmagnesium bromide 
• 766-51-8 2-Chloroanisole 
• 3761-92-0 n-hexylmagnesium bromide 
• 109-72-8 n-butyllithium 
• 612-15-7 o-methoxystyrene 
• 124960-14-1 1-((E)-Hex-1-enyl)-2-methoxy-benzene 

Downstream Products

• 111088-03-0 Bis-(3-hexyl-4-methoxy-phenyl)-iodonium; bromide 
• 3226-32-2 2-hexylphenol 
• 111088-04-1 (S)-3-[4-(3-Hexyl-4-methoxy-phenoxy)-3,5-diiodo-phenyl]-2-(2,2,2-trifluoro-acetylamino)-propionic acid methyl ester 
• 111087-75-3 (S)-2-Amino-3-[4-(3-hexyl-4-hydroxy-phenoxy)-3,5-diiodo-phenyl]-propionic acid 
• 18966-66-0 n-Hexyl-p-Bromophenol 
• 364068-95-1 C₅₇H₆₆O₉ 
• 364068-94-0 C₄₆H₅₄O₆ 
• 364068-92-8 carbonic acid tert-butyl ester 2-hexyl-6-iodo-4-[(triisopropylsilanyl)-ethynyl]-phenyl ester 
• 364068-91-7 acetic acid 2-hexyl-6-iodo-4-[(triisopropylsilanyl)-ethynyl]-phenyl ester 
• 364068-90-6 acetic acid 2-hexyl-4,6-diiodo-phenyl ester 
• 364068-89-3 2-hexyl-4,6-diiodo-phenol 

Relevant articles and documents

Microwave accelerated, Ni/C-catalyzed cross-couplings of in situ-derived zirconocenes

Both vinyl and alkyl zirconocenes undergo rapid couplings with aryl halides under heterogeneous conditions in a microwave reactor using Ni/C as catalyst. Ligand variations both in type and stoichiometry play major roles in the extent of conversion.

ortho-Directing Chromium Arene Complexes as Efficient Mediators for Enantiospecific C(sp2)–C(sp3) Cross-Coupling Reactions

A new strategy for the coupling of a broad scope of electronically diverse aromatics to boronic esters is reported. The coupling sequence, which relies on the directed ortho-lithiation of chromium arene complexes followed by boronate formation and oxidation, occurs with complete ortho-selectivity and enantiospecificity to give the coupling products in excellent yields and with high functional group tolerance. An intermediate chromium arene boronate complex was characterized by X-ray, NMR, and IR experiments to elucidate the reaction mechanism.

First Kumada reaction of alkyl chlorides using N-heterocyclic carbene/palladium catalyst systems

For the first time it is shown that N-heterocyclic carbenes are suitable ligands for the palladium-catalyzed coupling of alkyl chlorides with aryl Grignard reagents. A variety of simple as well as functionalized primary alkyl chlorides provide the corresponding alkyl benzenes in general in good to very good yield. By comparing the 1,3-dimesitylimidazol-2-ylidene (IMes) palladium(0) naphthoquinone complex with the previously known palladium phosphine catalyst for the model coupling reaction of 1-chlorohexane with phenylmagnesium bromide it is demonstrated that the new catalyst system is superior.