82096-08-0

Basic information

• Product Name: 5-Methyl-1-(4-trimethylsilanylmethyl-cyclohex-3-enyl)-hex-4-en-1-one
• Synonyms: 5-Methyl-1-(4-trimethylsilanylmethyl-cyclohex-3-enyl)-hex-4-en-1-one
• CAS NO: 82096-08-0
• Molecular Weight: 278.51
• Mol File: 82096-08-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 5-Methyl-1-(4-trimethylsilanylmethyl-cyclohex-3-enyl)-hex-4-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Methyl-1-(4-trimethylsilanylmethyl-cyclohex-3-enyl)-hex-4-en-1-one(82096-08-0)
• EPA Substance Registry System: 5-Methyl-1-(4-trimethylsilanylmethyl-cyclohex-3-enyl)-hex-4-en-1-one(82096-08-0)

Safety Data

• Hazardous Substances Data: 82096-08-0(Hazardous Substances Data)

Upstream product

• 24903-94-4 7-methyl-1,6-octadiene-3-one 
• 70901-64-3 trimethyl(2-methylenebut-3-enyl)silane 

Downstream Products

• 515-69-5 bisabolol 
• 4891-79-6 β-bisabolene 
• 76280-88-1 2-methyl-6-keto-6-(4-methyl-3-cyclohexen-1-yl)-2-hexene 
• 82096-15-9 5-Methyl-1-(4-methylene-cyclohexyl)-hex-4-en-1-one 
• 6009-90-1 iso-bisabolene 

Relevant articles and documents

CHEMISTRY OF THE ORGANOSILICON COMPOUNDS-165 2-TRIMETHYLSILYL-METHYL-1, 3-BUTADIENE-A VERSATILE BUILDING BLOCK FOR TERPENE SYNTHESIS

Two types of synthetically useful reactions of 2-trimethylsilylmethyl-1,3-butadiene (7) are discussed.Reactions of 7 with acid chlorides, aldehydes, ketones and acetals activated by a Lewis acid give isoprenylated compounds, while 7 undergoes the Diels-Alder reaction whit dienophiles.High regiospecificity of the reaction qualifies 7 for a versatile building block of terpene synthesis.