82655-59-2

Basic information

• Product Name: Benzenecarboximidoyl chloride, N-[(diethylamino)thioxomethyl]-
• CAS NO: 82655-59-2
• Molecular Formula: C12H15ClN2S
• Molecular Weight: 254.784
• Mol File: 82655-59-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzenecarboximidoyl chloride, N-[(diethylamino)thioxomethyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenecarboximidoyl chloride, N-[(diethylamino)thioxomethyl]-(82655-59-2)
• EPA Substance Registry System: Benzenecarboximidoyl chloride, N-[(diethylamino)thioxomethyl]-(82655-59-2)

Safety Data

• Hazardous Substances Data: 82655-59-2(Hazardous Substances Data)

Upstream product

• 58328-36-2 N,N-diethyl-N'-benzoyl-thiourea 
• 58676-54-3 bis(1,1-diethyl-3-benzoylthioureato) nickel(II) 

Downstream Products

• 122195-57-7 N-(p-phenyl)-N'-(diethylaminothiocarbonyl)benzamidin 
• 129117-67-5 N-(Diethylamino-thiocarbonyl)benzimidothioanhydrid 
• 90473-88-4 N-(diethylaminothiocarbonyl)benzamidine 
• 99265-63-1 cis-bis(1,1-diethyl-3-thiobenzoylthioureato) nickel(II) 
• 130750-25-3 2-({[(Z)-Morpholine-4-carbothioylimino]-phenyl-methyl}-amino)-benzoic acid 
• 130750-19-5 2-{[(Diethyl-thiocarbamoylimino)-phenyl-methyl]-amino}-benzoic acid 
• 130750-21-9 4-{[(Diethyl-thiocarbamoylimino)-phenyl-methyl]-amino}-benzoic acid 
• 130750-20-8 3-{[(Diethyl-thiocarbamoylimino)-phenyl-methyl]-amino}-benzoic acid 
• 90473-83-9 N-(N',N'-Diethylthiocarbamoyl)benzimido-O-methylester 
• 122195-53-3 N-(o-phenyl)-N'-(diethylaminothiocarbonyl)benzamidin 
• 129117-65-3 1,1-Diethyl-3-[1-methylselanyl-1-phenyl-meth-(Z)-ylidene]-thiourea 
• 129136-05-6 1,1-Diethyl-3-[1-methylsulfanyl-1-phenyl-meth-(Z)-ylidene]-thiourea 
• 130750-23-1 3-{[(Diethyl-thiocarbamoylimino)-phenyl-methyl]-amino}-benzoic acid ethyl ester 
• 90473-93-1 1,1-Diethyl-3-[1-phenyl-1-(pyridin-2-ylamino)-meth-(Z)-ylidene]-thiourea 

Relevant articles and documents

N-(AMINO-THIOCARBONYL)-BENZIMIDCHLORIDE

The reaction of nickel(II)chelates of N',N'-disubstituted N-benzoyl-thioureas with thionylchloride in a non polar solvent yields N-(amino-thiocarbonyl)-benzimide chlorides.

Oxidorhenium(V) complexes with tetradentate thiourea derivatives

Potentially tetradentate, binegative thiocarbamoylbenzamidines derived from o-phenylenediamines (H2L or H3L) are shown to be suitable ligand systems for oxidorhenium(V) cores. They readily react with (NBu 4)[ReOCl4] or [ReOCl3(PPh3) 2] under formation of monoxido complexes of the composition [ReO{(H)L}(Y)] with various co-ligands (Y = ReO4-, F 3CCO2-, Cl- or methanol) or μ-oxido dimers depending on the reaction conditions applied. Representative products were isolated and studied spectroscopically and by X-ray diffraction. Substitutions in the periphery of the ligands allow the introduction of a carboxylic substituent, which may serve as anchor group for future bioconjugation of appropriate rhenium (or technetium) complexes.

REAKTIONEN AN NICKEL(II)KOORDINIERTEN N-ACYLTHIOHARNSTOFFEN MIT SAEURECHLORIDEN: EIN EINFACHER ZUGANG FUER NEUE THIOHARNSTOFF-DERIVATE

The reaction of transition metal coordinated N,N-dialkylsubstituted N'-benzoyl thioureas with electrophilic agents differs from the reaction of the non-coordinated ligands.The nickel(II)chelates 1 form with organic acid chlorides RCOCl the N',N'-diacylate