82777-35-3Relevant articles and documents
Hydrosulfonylation of Unactivated Alkenes by Visible Light Photoredox Catalysis
Wang, Juan-Juan,Yu, Wei
supporting information, p. 9236 - 9240 (2019/11/19)
The anti-Markovnikov hydrosulfonylation of unactivated alkenes with sodium sulfinates was realized via [Ir(dF(CF3)ppy)2(dtbbpy)]PF6-mediated visible light photoredox catalysis. The presence of an acid such as acetic acid is essential for the reaction to take place. A variety of unactivated alkenes can be transformed into sulfones with good yield and high regioselectivity using this reaction, which is proposed to proceed by a radical mechanism.