829-53-8

Basic information

• Product Name: 2-methylprop-2-en-1-yl benzoate
• CAS NO: 829-53-8
• Molecular Formula: C₁₁H₁₂O₂
• Molecular Weight: 176.2118
• Mol File: 829-53-8.mol
• Article Data: 15

Chemical Properties

• Boiling Point: 260.1°C at 760 mmHg
• Flash Point: 114.9°C
• Density: 1.026g/cm³
• Vapor Pressure: 0.0125mmHg at 25°C
• Refractive Index: 1.511
• CAS DataBase Reference: 2-methylprop-2-en-1-yl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methylprop-2-en-1-yl benzoate(829-53-8)
• EPA Substance Registry System: 2-methylprop-2-en-1-yl benzoate(829-53-8)

Safety Data

• Hazardous Substances Data: 829-53-8(Hazardous Substances Data)

Upstream product

• 37952-93-5 N-benzoyl saccharin 
• 563-47-3 3-Chloro-2-methylpropene 
• 93-97-0 benzoic acid anhydride 
• 513-42-8 3-hydroxy-2-methyl-1-propene 
• 98-88-4 benzoyl chloride 
• 187884-23-7 α-(2-methylprop-2-enyloxy)benzyl hydroperoxide 
• 65-85-0 benzoic acid 
• 94421-52-0 Benzoic acid 2-methyl-2-nitro-3-phenylsulfanyl-propyl ester 
• 582-25-2 Potassium benzoate 
• 3290-74-2 5-methylene-2-phenyl-[1,3]dioxolane 
• 532-32-1 sodium benzoate 
• 88-65-3 2-bromobenzoic-acid 
• 10364-94-0 1-benzoylimidazole 

Downstream Products

• 86123-18-4 Benzoesaeure-(2-methyl-1-propenylester) 
• 90270-38-5 Benzoic acid 2-chloro-1,1-dimethyl-ethyl ester 
• 18292-38-1 2-methallyltrimethylsilane 
• 2078-12-8 trimethylsilyl benzoate 
• 81694-50-0 Benzoic acid 3-chloro-2-methyl-2-phenylselanyl-propyl ester 
• 6656-60-6 2-oxopropyl benzoate 
• 1445674-67-8 3-(tetrahydrofuran-2-yl)-2-methylpropyl benzoate 
• 1372715-59-7 1-methoxy-4-methyl-1-oxo-2-phenylpent-4-en-2-yl benzoate 
• 1188357-31-4 3-(benzyloxyimino)-3-cyano-2,2-dimethylpropyl benzoate 
• 1009091-32-0 2-azido-2-methylpropyl benzoate 
• 81694-54-4 2-(chloromethyl)allyl benzoate 
• 81694-55-5 Benzoic acid (E)-3-chloro-2-methyl-allyl ester 
• 245408-82-6 3-(benzoyloxymethyl)-2,2-dichloro-3-methylcyclobutanone 

Relevant articles and documents

A facile and versatile electro-reductive system for hydrodefunctionalization under ambient conditions

A general electrochemical system for reductive hydrodefunctionalization is described, employing the inexpensive and easily available triethylamine (Et3N) as a sacrificial reductant. This protocol is characterized by facile operation, sustainable conditions, and exceptionally wide substrate scope covering the cleavage of C-halogen, N-S, N-C, O-S, O-C, C-C and C-N bonds. Notably, the selectivity and capability of reduction can be conveniently switched by simple incorporation or removal of an alcohol as a co-solvent.

Direct Hydrofluorination of Methallyl Alkenes Using a Methanesulfonic Acid/Triethylamine Trihydrofluoride Combination

The use of a methanesulfonic acid/triethylamine trihydrofluoride combination for the direct hydrofluorination of methallyl-containing substrates is reported. Under those metal-free conditions that use readily available, cheap, and easy to handle reagents,

[Pd(μ-Br)(PtBu3)]2 as a highly active isomerization catalyst: Synthesis of enol esters from allylic esters

The dimeric Pd(I)-complex [Pd(μ-Br)(PtBu3)] 2 was found to be highly active for catalyzing double-bond migration in various substrates such as unsaturated ethers, alcohols, amides, and arenes, under mild conditions. It efficiently mediates the conversion of allylic esters into enol esters, rather than inserting into the allylic C-O bond. The broad applicability of this reaction was demonstrated with the synthesis of 22 functionalized enol esters.