83305-63-9Relevant articles and documents
α-Arylation of Carbonyl Compounds through Oxidative C?C Bond Activation
Li, Jing,Bauer, Adriano,Di Mauro, Giovanni,Maulide, Nuno
, p. 9816 - 9819 (2019)
A synthetically useful approach for the direct α-arylation of carbonyl compounds through a novel oxidative C?C bond activation is reported. This mechanistically unusual process relies on a 1,2-aryl shift and results in all-carbon quaternary centers. The transformation displays broad functional-group tolerance and can in principle also be applied as an asymmetric variant.