834-24-2

Basic information

• Product Name: 4-AMINOSTILBENE
• Synonyms: TIMTEC-BB SBB006905;P-AMINOSTILBENE;AKOS AUF0415;4-AMINOSTILBENE;4-STYRYL-PHENYLAMINE;4-STYRYL-ANILINE;4-STILBENAMINE;4-(2-phenylethenyl)-benzenamin
• CAS NO: 834-24-2
• Molecular Formula: C₁₄H₁₃N
• Molecular Weight: 195.26
• Product Categories: Stilbenes
• Mol File: 834-24-2.mol
• Article Data: 66

Chemical Properties

• Melting Point: 151°C
• Boiling Point: 321.94°C (rough estimate)
• Flash Point: 186.9ºC
• Appearance: /
• Density: 1.0778 (rough estimate)
• Vapor Pressure: 1.96E-05mmHg at 25°C
• Refractive Index: 1.6353 (estimate)
• PKA: 4.18±0.10(Predicted)
• Water Solubility: 5mg/L(room temperature)
• CAS DataBase Reference: 4-AMINOSTILBENE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-AMINOSTILBENE(834-24-2)
• EPA Substance Registry System: 4-AMINOSTILBENE(834-24-2)

Safety Data

• Hazard Codes: Xi,Xn
• Statements: 20/21/22-36/37/38-22
• Safety Statements: 26-36/37/39
• RTECS: WJ3500000
• HazardClass: IRRITANT
• Hazardous Substances Data: 834-24-2(Hazardous Substances Data)

Usage

General Description

4-Aminostilbene is a chemical compound with the molecular formula C14H13N. It is a derivative of stilbene and is commonly used in the synthesis of various organic compounds. 4-Aminostilbene is known for its fluorescent properties and is often used as a fluorescence probe in biological research. It is also used in the production of dyes, optical brighteners, and pharmaceuticals. Additionally, 4-Aminostilbene has been studied for its potential anti-cancer and anti-inflammatory properties, making it a compound of interest in the field of medicinal chemistry.

InChI:InChI=1/C14H13N/c15-14-10-8-13(9-11-14)7-6-12-4-2-1-3-5-12/h1-11H,15H2/b7-6+

Upstream product

• 140-29-4 phenylacetonitrile 
• 7647-01-0 hydrogenchloride 
• 1694-20-8 trans-4-nitrostilbene 
• 64-19-7 acetic acid 
• 100-42-5 styrene 
• 540-37-4 p-aminoiodobenzene 
• 106-47-8 4-chloro-aniline 
• 246177-84-4 1-azido-4-styrylbenzene 
• 4309-66-4 p-amino-trans-stilbene 
• 1942-30-9 4-(phenylethynyl)nitrobenzene 
• 536-74-3 phenylacetylene 
• 1849-25-8 4-phenylethynylphenylamine 
• 636-98-6 p-nitrobenzene iodide 
• 6624-53-9 (Z)-1-nitro-4-(2-phenylethenyl)-benzene 

Downstream Products

• 95081-69-9 stilben-4-yl-hydrazine 
• 14983-09-6 N-4-Stilbenyl-trifluoracetamid 
• 106550-96-3 1,5-Dimethyl-3-[(Z)-4-((E)-styryl)-phenylimino]-1,3-dihydro-indol-2-one 
• 1137-41-3 (4-aminophenyl)(phenyl)methanone 
• 33243-37-7 cis-4-benzamino-stilbene 
• 33243-37-7 N-Benzoyl-2-aminoanthracene 
• 4309-66-4 p-amino-trans-stilbene 
• 841-18-9 (E)-1-(4-acetamidophenyl)-2-phenylethene 
• 429689-40-7 (Z)-N-(4-(2-phenylethynyl)phenyl)acetamide 
• 1397252-93-5 4-phenethyl-N-(1-phenylethyl)aniline 
• 1262434-09-2 C₅₇H₉₄N₄O₈ 
• 61629-53-6 C₂₈H₂₃N 

Relevant articles and documents

NiFe2O4@SiO2@ZrO2/SO42-/Cu/Co nanoparticles: A novel, efficient, magnetically recyclable and bimetallic catalyst for Pd-free Suzuki, Heck and C-N cross-coupling reactions in aqueous media

The novel heterogeneous bimetallic nanoparticles of Cu-Co were synthesized based on magnetic nanoparticles, and the magnetic nanocatalyst was characterized by XRD, FE-SEM, EDX mapping, BET, TEM, HRTEM, FTIR, TGA, and VSM. This catalyst was successfully applied as a recyclable magnetically catalyst in Heck, Suzuki, and C-N cross-coupling reactions with various aryl halides (iodides, bromides, and chlorides as challengeable substrates), with olefins, phenylboronic acid, and amines, respectively. We considered the rise of synergetic effects from the different Lewis acid and Br?nsted acid sites present in the catalyst. The catalyst was synthesized with cheap, available materials and a simple synthesis method. The catalyst can be separated easily using an external magnet. It was recycled for more than ten runs without a sensible loss of its catalytic activity, and no significant leaching of the Cu and Co quantity was observed. The significant benefits of the method are high-level generality, simple operation, and there are no heavy metals and toxic solvents. This is a quick, easy, efficacious and environmentally friendly protocol, and no by-products are formed in the reaction. These features make it an appropriate practical alternative protocol. In comparison with recent works, the other advantage of this catalyst is the synthesis of a wide variety of C-C and C-N bond derivatives (more than 40 derivatives). The other significant advantage is the low temperature of the reaction and the use of the least possible amount of the catalyst (0.003 g). The efficiency was good to excellent and the catalyst selectivity has been high. We aspire that our study inspires more interest to design novel catalysts based on using low-cost metal ions (such as cobalt and copper) in the cross-coupling reactions. This journal is

A New Nitrogen Pd(II) Complex Immobilized on Magnetic Mesoporous Silica: A Retrievable Catalyst for C–C Bond Formation

Abstract: A new nitrogen ligand, i.e. 1,3-di-(o-aminophenoxy)-2-propyl propargyl ether (DPPE), has been synthesized and characterized. Magnetic mesoporous silica composite (MNP@SiO2-SBA) was obtained via embedding magnetite nano-particles (MNPs) between SBA-15 channels. DPPE palladium dichloride (MNP@SiO2-SBA-DPPE-Pd(II)) was then prepared via click chemistry and fully characterized. The activity and recyclability of supported magnetic Pd(II) catalyst were evaluated in Heck coupling reaction after optimizing the optimal reaction conditions including solvent, amount of catalyst, base and temperature. Aryl iodides and aryl bromides showed enhanced activity compared to those of aryl chlorides in the Heck reaction. The catalyst was easily separated magnetically, reused in five runs sequentially, and no significant loss of activity was observed. Graphic Abstract: [Figure not available: see fulltext.]

COPPER NANOPARTICLE BASED CHEMOSELECTIVE REDUCTION

The instant invention provides processes for a chemo selective reduction of a nitro group within a compound in the presence of other groups which can also be reduced. This aspect of the present invention provides an ammonia borane (AB) initiated chemoselective reduction process of a nitro group contained within a compound in the presence of a copper (Cu) nanoparticle based catalyst. The invention is also directed to Copper (Cu) nanoparticle (NP) based catalysts, selected from Cu/WOx, Cu/SiO2, and Cu/C; wherein x represents an integer having a value of from about 2 to about 3.5, used in the chemo selective reduction of a nitro group contained within a compound in the presence of other groups which can also be reduced.