836-87-3Relevant articles and documents
An efficient approach to 2-bromoalken-3-ols by regioselective bromohydroxylation reaction of simple allenes with NBS
Kong, Wangqing,Guo, Binjie,Fu, Chunling,Ma, Shengming
experimental part, p. 2278 - 2285 (2011/06/19)
A regioselective bromohydroxylation reaction of simple allenes affording 2-bromoalken-3-ols in moderate-to-good yields has been developed by using NBS as the electrophilic reagent in a mixture of 1,4-dioxane/H2O (1:1) at room temperature. Throu
The stability of butinoline
Unterhalt,Middelberg
, p. 492 - 494 (2007/10/02)
The stability of butinoline in alkaline and acidic solution was investigated. In alkaline solution the retrosynthesis to benzophenone and 3-pyrrolidino-1-propin was observed, in acidic solution the Meyer-Schuster rearrangement to the corresponding unsaturated amino ketone took place. Thermolysis gave 1,1-diphenyl-2-butin-1-ol in addition to the products of retrosynthesis.