84431-21-0

Basic information

• Product Name: (NO₂CCHNC(C₆H₄F)N(CH₂CH₂OH))2PtCl₂
• CAS NO: 84431-21-0
• Molecular Weight: 768.42
• Mol File: 84431-21-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (NO₂CCHNC(C₆H₄F)N(CH₂CH₂OH))2PtCl₂(CAS DataBase Reference)
• NIST Chemistry Reference: (NO₂CCHNC(C₆H₄F)N(CH₂CH₂OH))2PtCl₂(84431-21-0)
• EPA Substance Registry System: (NO₂CCHNC(C₆H₄F)N(CH₂CH₂OH))2PtCl₂(84431-21-0)

Safety Data

• Hazardous Substances Data: 84431-21-0(Hazardous Substances Data)

Upstream product

• 10025-99-7 potassium tetrachloroplatinate(II) 
• 4548-15-6 2-(p-fluorophenyl)-1-(2'-hydroxyethyl)-5-nitroimidazole 

Relevant articles and documents

Platinum(II) Complexes of Nitroimidazoles: Synthesis, Characterisation, and X-Ray Crystal Structures of cis-dichlorobisplatinum(II) and trans-dichlorobisplatinum(II)

A range of complexes of type 2X2> (where L is a substituted 5-nitroimidazole, and X2 is a dihalide or a dicarboxylate) has been prepared and characterised by a variety of methods, including 195Pt n.m.r. spectroscopy.These 5-nitroimidazole complexes had a cis stereochemistry as exemplified by the X-ray crystal-structure determination of cis-dichlorobisplatinum(II) .In addition, a number of analogous complexes of 2- and 4-nitroimidazoles were prepared.The 2-nitroimidazoles appeared to form the thermodynamically favoured trans complexes, rather than the kinetically favoured cis products.This was verified for trans-dichlorobisplatinum(II) 1/a>.This complex showed an unusual loss of planarity between the nitro-group and the imidazole ring, giving a dihedral angle of 45.6 deg.The geometry of the 4-nitroimidazole complexes was not determined.Co-ordination of the nitroimidazole ligand to PtII lowered the wavelength of the ?-?* electronic absorption band, and reduced the polarographic reduction potential by ca. 0.15-0.2V.