851513-48-9

Basic information

• Product Name: (S)-2-methyl-propane-2-sulfinic acid 1-(4-trifluoromethyl-phenyl)-meth-(E)-ylideneamide
• Synonyms: (S)-2-methyl-propane-2-sulfinic acid 1-(4-trifluoromethyl-phenyl)-meth-(E)-ylideneamide
• CAS NO: 851513-48-9
• Molecular Weight: 277.31
• Mol File: 851513-48-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (S)-2-methyl-propane-2-sulfinic acid 1-(4-trifluoromethyl-phenyl)-meth-(E)-ylideneamide(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-2-methyl-propane-2-sulfinic acid 1-(4-trifluoromethyl-phenyl)-meth-(E)-ylideneamide(851513-48-9)
• EPA Substance Registry System: (S)-2-methyl-propane-2-sulfinic acid 1-(4-trifluoromethyl-phenyl)-meth-(E)-ylideneamide(851513-48-9)

Safety Data

• Hazardous Substances Data: 851513-48-9(Hazardous Substances Data)

Upstream product

• 455-19-6 4-Trifluoromethylbenzaldehyde 
• 343338-28-3 (S)-2-methylpropane-2-sulfinamide 

Relevant articles and documents

A room-temperature protocol for the rhodium(I)-catalyzed addition of arylboron compounds to sulfinimines

(Chemical Equation Presented) The addition of organoboronic acids to chiral sulfinimines proceeds under mild conditions at room temperature, using Rh(I) catalysis in the absence of external phosphine ligands. Clean reaction only occurs in the presence of

Conversion of 1,3-disubstituted arenes to chiral α,α-diaryl methylammonium chlorides using arene borylation

A two-step conversion of 1,3-disubstituted arenes to chiral α,α-diaryl methylammonium chlorides is described. In this procedure, arenes are converted to aryl boronic esters by iridium-catalyzed borylation, and the aryl boronic esters are converted to enantioenriched amines by subsequent rhodium-catalyzed addition to chiral tert-butanesulfinimes.